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Report Date : 09/11/2010REVISION DATE: 09/11/2010 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING HARDENER FOR TWO COMPONENT Primer and Crack and hole filler COO-VARLockwood StreetHullHU2 0HN+44 (0) 1482 328053(T)+44 (0) 1482 219266(F)[email protected] Technical Department - 08.30 - 16.30 hrs Mon - Thurs, 08.30 - 15.00 hrs Fri as above Irritating to eyes. May cause sensitisation by skin contact.
CLASSIFICATION (1999/45) The Full Text for all R-Phrases are Displayed in Section 16 GENERAL INFORMATIONConsult a physician for specific advice.
NOTES TO THE PHYSICIANSymptomatic treatment is advisedINHALATIONMove into fresh air and keep at rest. Provide fresh air, warmth and rest, preferably in a comfortable upright sitting position. Consult a physician for specific advice.
INGESTIONImmediately rinse mouth and provide fresh air. DO NOT INDUCE VOMITING! Get medical attention immediately!SKIN CONTACTRemove contaminated clothing immediately and wash skin with soap and water. Get medical attention if irritation persists after washing. Wash contaminated clothing before reuse.
EYE CONTACTImmediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Get medical attention if any discomfort continues.
EXTINGUISHING MEDIAExtinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog. Do not use water as an extinguisher. DO NOT USE: Halon. Small fires: Use: Carbon dioxide or dry powder.
Report Date : 09/11/2010REVISION DATE: 09/11/2010 SPECIAL FIRE FIGHTING PROCEDURESBe aware of risk of fire re-starting, and risk of explosion. Decomposition under effect of heating. If involved in fire will support combustion. Avoid breathing fire vapours. Water spray should be used to cool containers.
UNUSUAL FIRE & EXPLOSION HAZARDSOXIDISING! May explode when heated or when exposed to flames or sparks.
SPECIFIC HAZARDSFire or high temperatures create: Toxic gases/vapours/fumes of: Carbon dioxide (CO2). Benzoic acid. Benzene, Diphenyl 2-ethylhexyl phosphate, Phenyl benzoate,PROTECTIVE MEASURES IN FIRESelf contained breathing apparatus and full protective clothing must be worn in case of fire.
PERSONAL PRECAUTIONSEnsure suitable personal protection (including respiratory protection) during removal of spillages in a confined area. Avoid inhalation of dust. Avoid contact with skin and eyes.
ENVIRONMENTAL PRECAUTIONSDo not allow to enter drains, sewers or watercourses.
SPILL CLEAN UP METHODSDampen spillage with water. Shovel into dry containers. Cover and move the containers. Flush the area with water. Avoid dust formation. Do not close container tightly. Risk of excess pressure build-up.
USAGE PRECAUTIONSAvoid spilling, skin and eye contact. Mechanical ventilation or local exhaust ventilation is required. Do not eat, drink or smoke when using the product. Avoid inhalation of dust. Use explosion proof electric equipment. Eliminate all sources of ignition.
STORAGE PRECAUTIONSKeep containers tightly closed. Store in closed original container at temperatures between 5°C and 25°C. Do not store near heat sources or expose to high temperatures. Store isolated from reducing agents. Store away from: Acids. Alkalis. heavy metal compounds(e.g. accelerators, driers, metal soaps.) Do not allow to dry out. Confinement must be avoided.
STORAGE CLASSFlammable liquid storage. The storage and use of this product is subject to the Dangerous Substances and Explosive Atmospheres Regulations (DSEAR). The requirements are given in the HSE Approved Code of Practice and Guidance, Storage od Danderous Substances: DSEAR. Up to 50 litres of liquids with a flashpoint below 32C may be kept in a workroom provided they are kept in closed containers in a marked, fire-resisting cupboard or bin. Larger quantities must be kept in a separate, marked storeroom conforming to the structural requirements contained in the HSE guidance note Storage of Flammable Liquids in Containers.
INGREDIENT COMMENTSWEL = Workplace Exposure Limits OES = Occupational Exposure Standard.
PROTECTIVE EQUIPMENT ENGINEERING MEASURESProvide adequate ventilation. Observe occupational exposure limits and minimize the risk of inhalation of dust. Provide explosion proof ventilation for high concentrations.
RESPIRATORY EQUIPMENTWear respirator if there is dust formation. Use respiratory equipment with particle filter, type P1.
Report Date : 09/11/2010REVISION DATE: 09/11/2010 HAND PROTECTIONUse suitable protective gloves if risk of skin contact. Neoprene gloves are recommended.
EYE PROTECTIONUse approved safety goggles or face shield.
OTHER PROTECTIONWear appropriate clothing to prevent any possibility of skin contact. Launder clothes before reuse.
HYGIENE MEASURESNo specific hygiene procedures noted, but good personal hygiene practices are always advisable, especially when working with chemicals.
STABILITYSADT- (Self accelerating decomposition temperature) is the lowest temperature at which self accelerating decomposition may occur with a substance in the packaging used for transport. A dangerous self-accelerating decomposition reaction and, under certain circumstances, explosion or fire can be caused by thermal decomposion at and above the following temperature: 55C. Contact with incompatible substances can cause decomposition at or below the SADT.
CONDITIONS TO AVOIDAvoid temperatures above 25 C. Confinement must be avoided. DO NOT ALLOW TO DRY OUT. Explosive when dry.
MATERIALS TO AVOIDAvoid contact with rust, iron copper. Contact with incompatible materials such as acids, alkalies, heavy metals and reducing agents will result in hazardous decomposition.
HAZARDOUS DECOMPOSITION PRODUCTSBenzoic acid. Benzene.
>5000 (Dibenzoyl peroxide) mg/kg (oral rat) >24.3; - (dibenzoyl peroxide) mg/l/4h (inh-rat) TOXICOLOGICAL INFORMATIONAmes test: Not mutagenic.
SKIN CONTACTSkin irritation is not anticipated when used normally. May cause sensitisation by skin contact.
EYE CONTACTIrritating to eyes.
2.0 (poecilla reticulata.) - Dibenzoyl peroxide DEGRADABILITYThe product is easily biodegradable.
Report Date : 09/11/2010REVISION DATE: 09/11/2010 GENERAL INFORMATIONWhen handling waste, consideration should be made to the safety precautions applying to handling of the product. Waste is classified as hazardous waste. Disposal to licensed waste disposal site in accordance with the local Waste Disposal Authority.
DISPOSAL METHODSDispose of waste and residues in accordance with local authority requirements. Incinerate in suitable combustion chamber.
WASTE CLASSIdeally this component should be mixed with the appropriate resin base and allowed to react fully producing a solid non hazardous waste.
This product is packed in accordance with the Limited Quantity Provisions of CDGCPL2, ADR and IMDG.
Organic peroxide type d, solid; (Dibenzoyl peroxide) May cause sensitisation by skin contact.
Keep container tightly closed in a cool place.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Wear suitable protective clothing, gloves and eye/face protection.
This material and its container must be disposed of as hazardous waste.
UK REGULATORY REFERENCESThe Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments. Chemicals (Hazard Information & Packaging) Regulations.
EU DIRECTIVESDangerous Substance Directive 67/548/EEC. Dangerous Preparations Directive 1999/45/EC. System of specific information relating to Dangerous Preparations. 2001/58/EC.
Report Date : 09/11/2010REVISION DATE: 09/11/2010 STATUTORY INSTRUMENTSThe Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Control of Substances Hazardous to Health.
APPROVED CODE OF PRACTICESafety Data Sheets for Substances and Preparations. Classification and Labelling of Substances and Preparations Dangerous for Supply. Dangerous Substances and Explosive Atmospheres Regulations 2002 [L138]GUIDANCE NOTESWorkplace Exposure Limits EH40. CHIP for everyone HSG(108).
NATIONAL REGULATIONSThe Chemicals (Hazard Information and Packaging for Supply) Regulations 2002. No. 1689. Commission Decision 2000/532/EC as amended by Decision 2001/118/EC establishing a list of wastes and hazardous waste pursuant to Council Directive 75/442/EEC on waste and Directive 91/689/EEC on hazardous waste with amendments.
GENERAL INFORMATIONOnly trained personnel should use this material.
REVISION COMMENTSIssued in new format for Reach compliance Issued in compliance with 30th & 31st ATP to Council Directive 67/548, as detailed in Commission Directive 2004/73/EC (1st ATP of EC Regulation 1272/2008) Corrections to Section 14, Transport Information Changes to brand logo.
ISSUED BYTechnical Dept. (P.E.)REVISION DATE REV. NO./REPL. SDS GENERATED 3SDS NO.
SAFETY DATA SHEET STATUSApproved.
DATE Extreme risk of explosion by shock, friction, fire or other sources of ignition.
May cause sensitisation by skin contact.
This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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