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Actellic smoke generators no. 20

Safety Data Sheet
PERMETHRIN SMOKE GENERATOR
IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND COMPANY OR
UNDERTAKING
Identification of the substance or preparation

Company identification
Company
Emergency Phone
+ 44 (0) 7885 561137 (24h)
COMPOSITION / INFORMATION ON INGREDIENTS
Chemical characteristic

Hazardous ingredients
Concentration
Risk phrases
(Classification according to Directive 67/548/EEC) (Classification according to Directive 67/548/EEC)
Information to exposure limit values - see section 8.

3. HAZARDS

IDENTIFICATION
Harmful if swallowed. Irritating to eyes and respiratory system. Toxic to aquatic organisms may cause long-term adverse effects in the aquatic environment. Ignites readily. Product burns without a flame to give a dense white harmful smoke. PERMETHRIN SMOKE GENERATOR Safety Data Sheet FIRST AID MEASURES

General advice: Remove contaminated, soaked clothing immediately and dispose of
safely.
Eye contact: Immediately irrigate with clean water, holding the eyelids apart, for at least
15 minutes. Obtain immediate medical attention.
Skin contact: Take off immediately all contaminated clothing. Wash skin immediately
with water, followed by soap and water. Such action is essential to minimise contact with
skin. Contaminated clothing should be laundered before re-issue. Apply Vitamin E cream
or simple toilet milks. When symptoms persist or in all cases of doubt seek medical
advice.
Inhalation: Remove patient from exposure, keep warm and at rest. Obtain medical
attention as a precaution.
Ingestion: If swallowed wash out mouth with water, seek medical advice immediately and
show the container, label or this Data Sheet, if possible. Do not induce vomiting.

Medical advice

Symptoms: Local: After skin contact: paresthesia (local). May cause skin and eye
irritation. Inhalation may provoke the following symptoms: irritation, cough.
Symptoms: Systemic: excitement, gastrointestinal discomfort, tremor, Dizziness,
headache, listlessness, nausea and vomiting, epigastric pain, muscular fasciculation of
limbs, unconsciousness, convulsions and coma (very high doses).
Risks: This product/preparation contains a pyrethroid. Must NOT be confused with
organophosphorus compounds.
Treatment: Local treatment: Initial treatment should be symptomatic and supportive. After
eye contact: Instillation of local anaesthetic drops e.g. 1% Amethocaine Hydrochloride eye
drops. Give Analgesics as necessary.
Treatment: Systemic treatment: Endotracheal intubation should be done and gastric
lavage performed, followed by administration of charcoal.
Monitoring of respiratory and cardiac functions.
ECG – monitoring (Electrocardiogram).
Check for pulmonary oedema in event of inhalation.
Keep airway clear, administer artificial respiration if necessary.
Against convulsions: Give diazepam: for adults 5-10mg intravenously as necessary until
fully sedated; for children 2.5mg i.v.
There is no antidote.
Contraindication: atropine
Contraindication: derivatives of adrenaline.
Recovery: Spontaneous.
FIRE FIGHTING MEASURES

Highly flammable. Ignites readily. Oxidising agent; may assist combustion.
Keep fire exposed containers cool by spraying with water.
Extinguishing media: For small fires, use foam, carbon dioxide or dry powder
extinguishant. For large fires, use foam or water-fog; avoid use of water jet. Contain run-
off water with, for example, temporary earth barriers.
Protective Equipment: A self-contained breathing apparatus and suitable protective
clothing should be worn in fire conditions.
PERMETHRIN SMOKE GENERATOR Safety Data Sheet ACCIDENTAL RELEASE MEASURES

Personal precautions: Ensure suitable personal protection during removal of spillages.
This means wearing a facemask that gives protection against toxic dusts, eye protection,
chemically resistant gloves (e.g. 0.6 mm nitrile), boots and coveralls. See also Section 8.
Clean up methods: Cover spillage with moist sand or soil. Transfer to a container for
disposal. Wash the spillage area with water. Washings must be prevented from entering
surface water drains.
Spillages or uncontrolled discharges into watercourses must be alerted to the appropriate
regulatory body.
HANDLING AND STORAGE

Handling
Read the label before use.
Do not breathe smoke. Avoid contact with skin and eyes. When using do not eat, drink or
smoke. Wash face and hands before eating, drinking or smoking.

Storage

Keep in original containers, tightly closed, out of reach of children. Keep away from food,
drink and animal feeding stuffs. Protect from frost.
Storage Life: Physically and chemically stable for at least 2 years when stored in the
original unopened sales container at ambient temperatures.
EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure Controls
Occupational exposure limits; Hazardous ingredients; Not applicable to field use
Permethrin MANUFACTURERS Standard, 8 hr TWA, 5 mg/m³.
Not applicable to field use.
Personal Protection
When using this product refer to the label for details. In all other cases, use the following
Personal Protective Equipment:
Respiratory protection: Wear suitable respiratory protective equipment if exposure to
levels above the occupational exposure limit is likely. Respiratory protective equipment
should conform to the appropriate EN standard.
Eye protection: Wear suitable eye/face protection conforming to EN 166.
Hand protection: Wear suitable gloves conforming to EN 374.
Body protection: Wear suitable protective clothing.
PERMETHRIN SMOKE GENERATOR Safety Data Sheet PHYSICAL AND CHEMICAL PROPERTIES
Physical State:
Melting Point:
Boiling point:
Flash-Point:
Autoignition temperature
Minimum Ignition temp.
Minimum Ignition:
Oxidizing properties:
Energy Explosive properties
Vapour pressure:
Solubility:
pH-value (quant.):
Partition coeff. (n-
octanol/water):
Density:

STABILITY AND REACTIVITY
Hazardous decomposition products: Combustion or thermal decomposition will evolve harmful and irritant vapours. 11. TOXICOLOGICAL
INFORMATION

Acute Oral Toxicity
LD50 (rat) ca. 2000 mg/kg
Test substance: Information given is based on data on the components and the toxicology
of similar products.
Acute Inhalation Toxicity
LC50 (rat) > 4.2 mg/l Exposure time : 4h
Remarks: Irritating to respiratory system

Acute Dermal Toxicity

LD50 (rat) >2000 mg/kg
Test substance: Information given is based on data on the components and the toxicology
of similar products.
Skin Irritation
Rabbit
Result: No skin irritation
Eye Irritation
Rabbit
Result: Irritating to eyes
Further Information
Cutaneous sensations may occur, such as burning or stinging on the face and mucosae.
However, these sensations cause no lesions and are of a transitory nature (max. 24
hours).
PERMETHRIN SMOKE GENERATOR Safety Data Sheet 12. ECOLOGICAL
INFORMATION

ECOTOXICITY
Toxicity to fish
Test substance: The value mentioned relates to the active ingredient Permethrin. Test substance: The value mentioned relates to the active ingredient Permethrin. Test substance: The value mentioned relates to the active ingredient Permethrin. Test substance: The value mentioned relates to the active ingredient Permethrin. 13. DISPOSAL
CONSIDERATIONS

Product: In accordance with current regulations may be taken to waste disposal site or
incineration plant, after consultation with site operator and/or with the responsible
authority.
Can be land filled or incinerated, when in compliance with local regulations.
Advice may be obtained from local waste regulation authority (part of the Environment
Agency in the UK)
Contaminated Packaging: packaging that cannot be cleaned should be disposed of as
product waste.
Empty containers can be land filled after cleaning, when in compliance with the
Environmental Protection (Duty of Care) Regulations 1991.

14. TRANSPORT

INFORMATION
PERMETHRIN SMOKE GENERATOR Safety Data Sheet
Rail / Road (RID / ADR)
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., (PERMETHRIN MIXTURE).
Sea (IMDG-Code)
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., (contains Permethrin 13.5%)
Air (ICAO / IATA)
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., (contains Permethrin 13.5%) 15. REGULATORY
INFORMATION
Classifications /
Hazard symbols
DANGEROUS FOR THE ENVIRONMENT
Risk phrases (R)
Irritating to eyes and respiratory system Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety phrases (S)
Keep away from food, drink and animal feeding stuffs. This material and its container must be disposed of in a safe way. Use appropriate containment to avoid environmental contamination. Special label
To avoid risks to man and the environment, comply with the instructions for use. 16. OTHER
INFORMATION
Further information

PERMETHRIN SMOKE GENERATOR Safety Data Sheet Text of R phrases mentioned in Section 2: R9 Explosive when mixed with combustible material R20/22 Harmful by inhalation and if swallowed R22
The information contained herein is based on the present state of our knowledge
and is intended to describe our products from the point of view of safety
requirements. It should not therefore be construed as guaranteeing specific
properties.

PERMETHRIN SMOKE GENERATOR Safety Data Sheet

Source: http://www.octaviushunt.co.uk/wp-content/uploads/2013/08/permethrin-smoke-generator-safety-data.pdf

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