Microsoft word - farmalinx diflucan 500 herbicide.doc

Product Name: Farmalinx DIFLUCAN 500 Herbicide
Page: 1 of 5
This revision issued: September, 2013
Section 1 - Identification of The Material and Supplier
FARMALINX Pty Ltd
Phone: 02 9389 2455
Level 25, Suite 2506 (Tower 2)
Fax: 02 9389 2844
101 Grafton Street
www.farmalinx.com
Bondi Junction, NSW 2022
Chemical nature:
Diflufenican is a fluoridated carboxamide derivative. Trade Name:
Farmalinx DIFLUCAN 500 Herbicide
APVMA Code: 69281
Product Use:
Agricultural herbicide for use as described on the product label. Creation Date:
September, 2013
This version issued:
September, 2013 and is valid for 5 years from this date.
Section 2 - Hazards Identification
Statement of Hazardous Nature
This product is classified as: Not classified as hazardous according to the criteria of SWA.
Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code. Risk Phrases: Not Hazardous - No criteria found.
Safety Phrases: S23, S36, S24/25. Do not breathe mists or spray. Wear suitable protective clothing. Avoid contact
with skin and eyes.
SUSMP Classification: None allocated.
ADG Classification: None allocated. Not a Dangerous Good under the ADG Code.
UN Number: None allocated
GHS Signal word: NONE. Not hazardous.
RESPONSE
P353: Rinse skin or shower with water. P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P332+P313: If skin irritation occurs: Get medical advice. P337+P313: If eye irritation persists: Get medical advice. P391: Collect spillage. P370+P378: In case of fire, use carbon dioxide, dry chemical, foam, water fog. P402+P404: Store in a dry place. Store in a closed container. P403+P235: Store in a well-ventilated place. Keep cool. DISPOSAL
P501: Dispose of contents and containers as specified on the registered label. Emergency Overview
Physical Description & Colour: Viscous light brown liquid suspension.
Odour: Mild odour.
Major Health Hazards: no significant risk factors have been found for this product.
Potential Health Effects
Inhalation:
Short Term Exposure: Available data indicates that this product is not harmful. However product may be mildly
irritating, although unlikely to cause anything more than mild transient discomfort.
Long Term Exposure: No data for health effects associated with long term inhalation.
Skin Contact:
Short Term Exposure: Available data indicates that this product is not harmful. It should present no hazards in
normal use. However product may be irritating, but is unlikely to cause anything more than mild transient discomfort.
Long Term Exposure: No data for health effects associated with long term skin exposure.
SAFETY DATA SHEET
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Farmalinx DIFLUCAN 500 Herbicide
Page: 2 of 5
This revision issued: September, 2013
Eye Contact:
Short Term Exposure: This product is believed to be mildly irritating, to eyes, but is unlikely to cause anything
more than mild transient discomfort.
Long Term Exposure: No data for health effects associated with long term eye exposure.
Ingestion:
Short Term Exposure: Significant oral exposure is considered to be unlikely. However, this product is believed to
be mildly irritating to mucous membranes but is unlikely to cause anything more than mild transient discomfort.
Long Term Exposure: No data for health effects associated with long term ingestion.
Carcinogen Status:
SWA: No significant ingredient is classified as carcinogenic by SWA.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: No significant ingredient is classified as carcinogenic by IARC.
Section 3 - Composition/Information on Ingredients
Ingredients
TWA (mg/m3) STEL
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non hazardous ingredients are also possible. The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly. Section 4 - First Aid Measures
General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by
this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all
times. Have this SDS with you when you call.
Inhalation: No first aid measures normally required. However, if inhalation has occurred, and irritation has
developed, remove to fresh air and observe until recovered. If irritation becomes painful or persists more than about
30 minutes, seek medical advice.
Skin Contact: Wash gently and thoroughly with water (use non-abrasive soap if necessary) for 5 minutes or until
chemical is removed.
Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 5 minutes or until
the product is removed, while holding the eyelid(s) open. Obtain medical advice immediately if irritation occurs. Take
special care if exposed person is wearing contact lenses.
Ingestion: If product is swallowed or gets in mouth, do NOT induce vomiting; wash mouth with water and give some
water to drink. If symptoms develop, or if in doubt contact a Poisons Information Centre or a doctor.
Section 5 - Fire Fighting Measures
Fire and Explosion Hazards: The major hazard in fires is usually inhalation of heated and toxic or oxygen
deficient (or both), fire gases. There is no risk of an explosion from this product under normal circumstances if it is
involved in a fire.
This product is likely to decompose only after heating to dryness, followed by further strong heating.
Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.
Extinguishing Media: In case of fire, use carbon dioxide, dry chemical, foam, water fog.
Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade.
Flash point:
Upper Flammability Limit:
Lower Flammability Limit:
Autoignition temperature:
Flammability Class:
SAFETY DATA SHEET
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Farmalinx DIFLUCAN 500 Herbicide
Page: 3 of 5
This revision issued: September, 2013
Section 6 - Accidental Release Measures
Accidental release: Minor spills do not normally need any special cleanup measures. In the event of a major spill,
prevent spillage from entering drains or water courses. As a minimum, wear overalls, goggles and gloves. Suitable
materials for protective clothing include rubber, PVC. Eye/face protective equipment should comprise as a minimum,
protective goggles. If there is a significant chance that vapours or mists are likely to build up in the cleanup area, we
recommend that you use a respirator. Usually, no respirator is necessary when using this product. However, if you
have any doubts consult the Australian Standard mentioned below (section 8). Otherwise, not normally necessary.
Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill
is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains
or waterways. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage,
and dispose of promptly. Recycle containers wherever possible after careful cleaning. Refer to product label for
specific instructions. After spills, wash area preventing runoff from entering drains. If a significant quantity of material
enters drains, advise emergency services. Full details regarding disposal of used containers, spillage and unused
material may be found on the label. If there is any conflict between this SDS and the label, instructions on the label
prevail. Ensure legality of disposal by consulting regulations prior to disposal. Thoroughly launder protective clothing
before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage
Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check
Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed.
The measures detailed below under "Storage" should be followed during handling in order to minimise risks to
persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible
materials listed in Section 10.
Storage: Protect this product from light. Store in the closed original container in a dry, cool, well-ventilated area out
of direct sunlight. Make sure that the product does not come into contact with substances listed under
"Incompatibilities" in Section 10. Some liquid preparations settle or separate on standing and may require stirring
before use. Check packaging - there may be further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection
The following Australian Standards will provide general advice regarding safety clothing and equipment: Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501
set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.
SWA Exposure Limits
TWA (mg/m3) STEL
Exposure limits have not been established by SWA for any of the significant ingredients in this product. No special equipment is usually needed when occasionally handling small quantities. The following instructions are
for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.
Ventilation: This product should only be used in a well ventilated area. If natural ventilation is inadequate, use of a
fan is suggested.
Eye Protection: Eye protection such as protective glasses or goggles is recommended when this product is being
used.
Skin Protection: You should avoid contact even with mild skin irritants. Therefore you should wear suitable
impervious elbow-length gloves and facial protection when handling this product. See below for suitable material
types.
Protective Material Types: We suggest that protective clothing be made from the following materials: rubber,
PVC.
Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned above. Otherwise, not normally necessary.
Safety deluge showers should, if practical, be provided near to where this product is being handled commercially.
Section 9 - Physical and Chemical Properties:
Physical Description & colour: Viscous light brown liquid suspension.
Odour:
Boiling Point:
Freezing/Melting Point:
No specific data. Liquid at normal temperatures. Volatiles:
Vapour Pressure:
2.37 kPa at 20°C (water vapour pressure). Vapour Density:
Specific Gravity: 1.19-1.20
SAFETY DATA SHEET
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Farmalinx DIFLUCAN 500 Herbicide
Page: 4 of 5
This revision issued: September, 2013
Water Solubility:
pH: Approx
Volatility: No
Odour Threshold: No
Evaporation Rate:
Coeff Oil/water Distribution: No
Autoignition temp:
Section 10 - Stability and Reactivity
Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have
any doubts, contact the supplier for advice on shelf life properties.
Conditions to Avoid: Protect this product from light. Store in the closed original container in a dry, cool, well-
ventilated area out of direct sunlight.
Incompatibilities: strong acids, strong bases, strong oxidising agents.
Fire Decomposition: This product is likely to decompose only after heating to dryness, followed by further strong
heating. Combustion forms carbon dioxide, and if incomplete, carbon monoxide and possibly smoke. Water is also
formed. May form nitrogen and its compounds, and under some circumstances, oxides of nitrogen. Occasionally
hydrogen cyanide gas in reducing atmospheres. May form hydrogen fluoride gas and other compounds of fluorine.
Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision,
disturbance of judgment, and unconsciousness followed by coma and death.
Polymerisation: This product will not undergo polymerisation reactions.
Section 11 - Toxicological Information
Local Effects:
Target Organs:
There is no data to hand indicating any particular target organs. Classification of Hazardous Ingredients
No ingredient mentioned in the HSIS Database is present in this product at hazardous concentrations.
Diflufenican:
LD50 Oral, Rat >2000mg/kg
Section 12 - Ecological Information
This product is harmful to aquatic organisms. This product is biodegradable. It will not accumulate in the soil or water or cause long term problems. Birds: LD50 quail: >2150mg/kg
Fish: LC50 rainbow trout (Oncorhynchus mykiss): 56-100mg/L
LC50 carp (Cyprinus carpio): 105mg/L
Algae: EC50 10mg/L
Daphnia: EC50 >10mg/L
Section 13 - Disposal Considerations
Disposal: Special help is available for the disposal of Agricultural Chemicals. The product label will give general
advice regarding disposal of small quantities, and how to cleanse containers. However, for help with the collection of
unwanted rural chemicals, contact ChemClear 1800 008 182 http://www.chemclear.com.au/ and for help with the
disposal of empty drums, contact DrumMuster http://www.drummuster.com.au/ where you will find contact details for
your area.
Section 14 - Transport Information
ADG Code: This product is not classified as a Dangerous Good. No special transport conditions are necessary
unless required by other regulations.
Section 15 - Regulatory Information
AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
SAFETY DATA SHEET
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Farmalinx DIFLUCAN 500 Herbicide
Page: 5 of 5
This revision issued: September, 2013
Section 16 - Other Information
This SDS contains only safety-related information. For other data see product literature.
Acronyms:
Australian Code for the Transport of Dangerous Goods by Road and Rail (7th edition) Australian Inventory of Chemical Substances Safe Work Australia, formerly ASCC and NOHSC CAS number
Chemical Abstracts Service Registry Number Hazchem Code
Emergency action code of numbers and letters that provide information to emergency services especially firefighters International Agency for Research on Cancer R-Phrase Risk
Standard for the Uniform Scheduling of Medicines & Poisons UN Number United
THIS SDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD STATEMENT: INFORMATION OF THE PRODUCT AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS SDS IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE. IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST. Please read all labels carefully before using product. This SDS is prepared in accord with the SWA document “Preparation of Safety Data Sheets for Hazardous Chemicals - Code of Practice” (December 2011) Copyright Kilford & Kilford Pty Ltd, September, 2013. http://www.kilford.com.au/ Phone (02)9251 4532 SAFETY DATA SHEET
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)

Source: http://www.farmalinx.com.au/SiteMedia/w3svc1005/Uploads/Documents/DIFLUCAN%20500-msds.pdf