Material Safety Data Sheet SPA WORLD LITHIUM SANITIZER 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER Product Name Company Name
POOL & SPA POPPITS PTY. LTD. (ABN 53 569 007 940)
Emergency Tel. Telephone/Fax Recommended Use
Used as a sanitising agent in swimming pools. 2. HAZARDS IDENTIFICATION Classification
DANGEROUS GOODS. Hazard classification according to the criteria of NOHSC. Dangerous goods classification according to the Australia Dangerous Goods Code. Risk Phrase(s)
R21 Harmful in contact with skin. R23 Toxic by inhalation. R34 Causes burns. R41 Risk of serious damage to eyes. R8 Contact with combustible material may cause fire. Safety Phrase(s)
S17 Keep away from combustible material. S2 Keep out of reach of children. S22 Do not breathe dust. S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S38 If insufficient ventilation, wear suitable respiratory equipment. S45 In case of accident or if you feel unwell seek medical advice immediately
3. COMPOSITION/INFORMATION ON INGREDIENTS Ingredients Proportion
components fraction of total massIngredients
4. FIRST AID MEASURES Inhalation
Remove the source of contamination or move the affected person to fresh air. Ensure airways are clear. Apply artificial respiration if not breathing. Seek medical attention. Ingestion
Do NOT induce vomiting. Wash out mouth with water. Seek medical attention.
Wash affected area thoroughly with soap and plenty of water. Remove contaminated clothing and wash before reuse or discard. If symptoms develop seek medical attention.
If in eyes, hold eyelids apart and flush the eyes continuously with running water. Continue flushing for at least 15 minutes until all contaminants are washed off completely. Seek medical attention. First Aid Facilities
Eye wash and normal washroom facilities. Advice to Doctor Material Safety Data Sheet SPA WORLD LITHIUM SANITIZER Other Information
For advice in an emergency contact the Australian Poisons Information Centre on 13 1126 or a doctor, at once. 5. FIRE FIGHTING MEASURES Suitable Extinguishing Media Hazards from
Under fire conditions thermal decomposition may result in the release of toxic
Combustion
and/or irritating fumes including oxygen, lithium hydroxide, lithium
Products Specific Hazards
Oxidising agent, contact with combustible material may cause fire. Heating under fire conditions may result in the violent rupture of product containers. Hazchem Code Precautions in
Fire-fighters should wear full protective clothing and self contained
connection with Fire
breathing apparatus (SCBA) operated in positive pressure mode. Water spray may be used to keep fire exposed containers cool. Unsuitable
Dry chemicals, carbon dioxide or halon. Extinguishing Media 6. ACCIDENTAL RELEASE MEASURES Emergency
Avoid breathing dust and increase ventilation. If possible prevent spillage
Procedures
contacting combustible substances. Wear appropriate personal protective equipment and clothing to prevent exposure. Evacuate all unprotected personnel. Sweep up/shovel material avoiding dust generation or use dustless methods such as vacuum. If large quantities of this material enters the waterways contact the Environmental Protection Authority, or your local Waste Management Authority. 7. HANDLING AND STORAGE Precautions for Safe
Wear appropriate protective equipment to prevent exposure. Prevent the
Handling
creation of dusts. Practice good personal hygiene, that is, always wash hands after handling, and before eating, drinking, smoking or using the toilet facilities. Conditions for Safe
Store in a cool, dry, well-ventilated area away from foodstuffs. Store away
from incompatible materials. Protect from moisture. Keep containers closed when not in use and securely sealed and protected against physical damage. Inspect regularly for deficiencies such as damage or leaks. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION National Exposure
No exposure standards have been established for this material by the National
Standards
Occupational Health & Safety Commission (NOHSC) Australia. The exposure limit for dust not otherwise specified as provided by NOHSC is listed as follows:Substance TWA STEL ppm mg/m³ ppm mg/m³Dust (inspirable fraction) - 10 - -TWA (Time Weighted Average): The average airborne concentration of a particular substance when calculated over a normal eight-hour working day, for a five-day week. STEL (Short Term Exposure Limit): The average airborne concentration over a 15 minute period which should not be exceeded at any time during a normal eight-hour workday. Biological Limit Values Engineering
Good ventilation adequate to keep airborne concentrations below the exposure
Controls
standard is required. Where dusts are generated during use, a local exhaust ventilation system, drawing dust away from breathing zone, should be used. Respiratory
Where ventilation is inadequate and dusts are generated, the use of an
Protection
approved respirator with filter complying with AS/NZS 1715 and AS/NZS 1716 is required. Eye Protection
Safety glasses with side shields or chemical goggles should be worn. Final choice of appropriate eye/face protection will vary according to individual circumstances. Eye protection devices should conform with Australian/New Zealand Standard AS/NZS 1337 - Eye Protectors for Industrial Applications. Material Safety Data Sheet SPA WORLD LITHIUM SANITIZER Hand Protection
Wear impervious gloves such as rubber conforming to AS/NZS 2161: Occupational protective gloves. Consult glove suppliers to determine other appropriate glove types and, if necessary, test gloves before use. Body Protection
Suitable protective workwear, e.g. cotton overalls buttoned at neck and wrist. Industrial clothing should conform to the specifications detailed in AS/NZS 2919: Industrial clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Melting Point Boiling Point Solubility in Water Specific Gravity Vapour Pressure Vapour Density (Air=1) Flash Point Flammability Auto-Ignition Temperature Flammable Limits - Lower Flammable Limits - 10. STABILITY AND REACTIVITY Chemical Stability
Stable under normal conditions of storage and handling. Conditions to Avoid Incompatible
Acids, oxidisable and combustible materials. Materials Hazardous
Thermal decomposition may result in the release of toxic and/or irritating
Decomposition
fumes including oxygen, lithium hydroxide, lithium chlorates. Products Hazardous Polymerization 11. TOXICOLOGICAL INFORMATION Toxicology
The toxicity datum available for this product is as follows:
Information
LD50 (Inhalation, Rat): 1,800 mg/LLD50 (Oral, Rat): 1,500 ± 270 mg/kgLD50 (Dermal, Rabbit): 8,100 mg/kg
Inhalation
Toxic by inhalation. Corrosive to respiratory tract and mucous membranes. Ingestion
Ingestion can cause pain, nausea, vomiting, diarrhoea and chemical burns to the mouth, throat and stomach.
Harmful in contact with skin. Will cause burns in contact with the skin, resulting in redness and swelling. More serious effects may occur especially if the skin is moist resulting in blistering, severe lesions and possible permanent tissue damage (scarring).
Risk of serious damage to eyes. Eye contact will cause stinging, blurring, tearing, severe pain and possible permanent corneal damage. 12. ECOLOGICAL INFORMATION Ecotoxicity
No data is available for this material. Material Safety Data Sheet SPA WORLD LITHIUM SANITIZER Persistence / Degradability Mobility Bioaccumulative Potential Environ. Protection
Do not allow product to enter drains, waterways or sewers. 13. DISPOSAL CONSIDERATIONS Disposal
The disposal of the spilled or waste material must be done in accordance with
Considerations
applicable local and national regulations. 14. TRANSPORT INFORMATION Transport
This material is classified as a Class 5.1 Dangerous Good according to the
Information
Australian Code for the Transport of Dangerous Goods. Class 5.1 oxidising agents shall not be loaded or packed in the same vehicle or freight as:- Explosives (class 1)- Flammable Gases (class 2.1)- Toxic Gases (class 2.3)- Flammable Liquids (class 3),- Flammable Solids (4.1)- Spontaneously Combustible Substances (class 4.2)- Dangerous When Wet Substances (class 4.3)- Organic Peroxides (class 5.2)- Toxic Substances (class 6)(where the toxic substances are fire risk substances)- Radioactive Substances (class 7)- Corrosive Substances (class 8)- Miscellaneous Dangerous Goods (class 9)(where the miscellaneous dangerous goods are fire risk substances), or Fire Risk substances or Combustible Liquids. U.N. Number Proper Shipping Name DG Class Hazchem Code Packaging Method Packing Group IERG Number 15. REGULATORY INFORMATION Regulatory
Classified as Hazardous according to criteria of National Occupational Health
Information
& Safety Commission (NOHSC), Australia. Classified as a Scheduled Poison S6 according to the Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP). Poisons Schedule Hazard Category 16. OTHER INFORMATION Date of preparation or last revision of MSDS
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