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SAFETY DATA SHEET (REGULATION (EC) No 1907/2006 - REACH) SAFETY DATA SHEET
(REACH regulation (EC) n° 1907/2006 - n° 453/2010) SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
COMPANY/UNDERTAKING
1.1. Product identifier
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.3. Details of the supplier of the safety data sheet
Address: 1ere avenue 2065m LID.06511.CARROS.France.
Telephone: 04-92-08-73-00. Fax: 04-92-08-76-61.
[email protected] - Tel: 06-19-69-39-27 1.4. Emergency telephone number : +33 (0)1 45 42 59 59.
Association/Organisation: INRS / ORFILA http://www.centres-antipoison.net.
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
In compliance with EC regulation No. 1272/2008 and its amendments.
Specific target organ toxicity (single exposure), Category 3.
Hazardous to the aquatic environment - Acute hazard, Category 1.
Hazardous to the aquatic environment - Chronic hazard, Category 1.
In compliance with directives 67/548/EEC, 1999/45/EC and their amendments.
Possibility of skin sensitisation. The mixture may also irritate the skin and prolonged contact may aggravate this effect.
Vapors may cause drowsiness and dizziness.
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
2.2. Label elements
In compliance with EC regulation No. 1272/2008 and its amendments.
May cause an allergic skin reaction.
Very toxic to aquatic life with long lasting effects.
If medical advice is needed, have product container or label at hand.
- Made under licence of European Label System® MSDS software from InfoDyne - http://www.infodyne.fr - SAFETY DATA SHEET (REGULATION (EC) No 1907/2006 - REACH) Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
Ground/bond container and receiving equipment.
Take precautionary measures against static discharge.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Use only outdoors or in a well-ventilated area.
Contaminated work clothing should not be allowed out of the workplace.
Wear protective gloves/protective clothing/eye protection/face protection.
IF ON SKIN: Wash with plenty of soap and water.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Call a POISON CENTER or doctor/physician if you feel unwell.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
In case of fire: Use . for extinction.
Store in a well-ventilated place. Keep container tightly closed.
In compliance with directives 67/548/EEC, 1999/45/EC and their amendments.
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
May cause sensitisation by skin contact.
Vapours may cause drowsiness and dizziness.
If swallowed, seek medical advice immediately and show this container or label.
Keep away from food, drink and animal feedingstuffs.
2.3. Other hazards
Do not handle this product in case of known sensitization to a raw material as permethrin or py SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1. Substances
No substances fulfil the criteria set forth in annexe II section A of the REACH regulation (EC) n° 190 7/2006.
3.2. Mixtures
Composition :
- Made under licence of European Label System® MSDS software from InfoDyne - http://www.infodyne.fr - SAFETY DATA SHEET (REGULATION (EC) No 1907/2006 - REACH) H:226-360D.1B-335-315-318R: 61.G2-10-37/38-41 SECTION 4: FIRST AID MEASURES
As a general rule, in case of doubt or if symptoms persist, always call a doctor.
NEVER induce swallowing by an unconscious person.
4.1. Description of first aid measures
In the event of exposure by inhalation:
In the event of massive inhalation, remove the person exposed to fresh air. Keep warm and at rest.
If the person is unconscious, place in recovery position. Notify a doctor in all events, to ascertain whether observation and supportive hospital care will be necessary.
If breathing is irregular or has stopped, effect mouth-to-mouth resuscitation and call a doctor.
In the event of splashes or contact with skin:
Remove contaminated clothing and wash the skin thoroughly with soap and water or a recognised cleaner.
Watch out for any remaining product between skin and clothing, watches, shoes, etc.
In the event of an allergic reaction, seek medical attention.
If the contaminated area is widespread and/or there is damage to the skin, a doctor must be consulted or the patient transferred to hospital In the event of swallowing:
Do not give the patient anything orally.
In the event of swallowing, if the quantity is small (no more than one mouthful), rinse the mouth with water and consult a doctor.
Seek medical attention immediately, showing the label.
4.2. Most important symptoms and effects, both acute and delayed
4.3. Indication of any immediate medical attention and special treatment needed
SECTION 5: FIREFIGHTING MEASURES
Chemical powders, carbon dioxide and other extinguishing gas are suitable for small fires.
5.1. Extinguishing media
Keep packages near the fire cool, to prevent pressurised containers from bursting.
Suitable methods of extinction
Prevent the effluent of fire-fighting measures from entering drains or waterways.
Unsuitable methods of extinction
5.2. Special hazards arising from the substance or mixture
A fire will often produce a thick black smoke. Exposure to decomposition products may be hazardous to health.
In the event of a fire, the following may be formed: - Made under licence of European Label System® MSDS software from InfoDyne - http://www.infodyne.fr - SAFETY DATA SHEET (REGULATION (EC) No 1907/2006 - REACH) 5.3. Advice for firefighters
Fire-fighting personnel are to be equipped with autonomous insulating breathing apparatus.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Consult the safety measures listed under headings 7 and 8.
For non fire-fighters
Avoid any contact with the skin and eyes.
If a large quantity has been spilt, evacuate all personnel and only allow intervention by trained operators equipped with safety apparatus.
For fire-fighters
Fire-fighters will be equipped with suitable personal protective equipment (See section 8).
6.2. Environmental precautions
Contain and control the leaks or spills with non-combustible absorbent materials such as sand, earth, vermiculite, diatomaceous earth in drums for waste disposal.
Prevent any material from entering drains or waterways.
If the product contaminates waterways, rivers or drains, alert the relevant authorities in accordance with statutory procedures Use drums to dispose of collected waste in compliance with current regulations (see section 13).
6.3. Methods and material for containment and cleaning up
Clean preferably with a detergent, do not use solvents.
6.4. Reference to other sections
SECTION 7: HANDLING AND STORAGE
Requirements relating to storage premises apply to all facilities where the mixture is handled.
Individuals with a history of skin sensitisation should not, under any circumstance, handle this mixture.
7.1. Precautions for safe handling
Remove and wash contaminated clothing before re-using.
Remove contaminated clothing and protective equipment before entering eating areas.
Fire prevention:
Prevent the formation of flammable or explosive concentrations in air and avoid vapor concentrations higher than the occupational exposure limits.
Prevent the accumulation of electrostatic charges with connections to earth The mixture can become electrostatically charged: always earth during decanting operations. Wear antistatic shoes and clothing and floors should be electrically conductive.
Use the mixture in premises free of naked flames or other sources of ignition and ensure that electrical equipment is suitably protected.
Keep packages tightly closed and away from sources of heat, sparks and naked flames.
Do not use tools which may produce sparks. Do not smoke.
Prevent access by unauthorised personnel.
Recommended equipment and procedures:
For personal protection, see section 8.
Observe precautions stated on label and also industrial safety regulations Avoid inhaling vapors. Carry out any industrial operation which may give rise to this in a sealed apparatus.
Provide vapor extraction at the emission source and also general ventilation of the premises Also provide breathing apparatus for certain short tasks of an exceptional nature and for emergency interventions In all cases, recover emissions at source Prohibited equipment and procedures:
No smoking, eating or drinking in areas where the mixture is used.
- Made under licence of European Label System® MSDS software from InfoDyne - http://www.infodyne.fr - SAFETY DATA SHEET (REGULATION (EC) No 1907/2006 - REACH) 7.2. Conditions for safe storage, including any incompatibilities
Keep the container tightly closed in a dry place.
Keep the container tightly closed in a dry, well-ventilated place Keep away from all sources of ignition - do not smoke.
Keep well away from all sources of ignition, heat and direct sunlight Avoid accumulation of electrostatic charges.
Packaging
Always keep in packaging made of an identical material to the original 7.3. Specific end use(s)
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
Occupational exposure limits:
- European Union (2009/161/EU, 2006/15/EC, 2000/39/EC, 98/24/EC) - ACGIH TLV (American Conference of Governmental Industrial Hygienists, Threshold Limit Values, 2010): - Germany - AGW (BAuA - TRGS 900, 21/06/2010): - France (INRS - ED984:2007 and French Order of 30/06/2004): 8.2. Exposure controls
Personal protection measures, such as personal protective equipment
Pictogram(s) indicating the obligation of wearing personal protective equipment (PPE): Use personal protective equipment that is clean and has been properly maintained.
Store personal protective equipment in a clean place, away from the work area.
Never eat, drink or smoke during use. Remove and wash contaminated clothing before re-using. Ensure that there is adequate ventilation, especially in confined areas.
- Eye / face protection
Use eye protectors designed to protect against liquid splashes Before handling, wear safety goggles in accordance with standard EN166.
- Hand protection
Use suitable protective gloves that are resistant to chemical agents in accordance with standard EN374.
Gloves must be selected according to the application and duration of use at the workstation.
Protective gloves need to be selected according to their suitability for the workstation in question: other chemical products that may be handled, necessary physical protections (cutting, pricking, heat protection), level of dexterity required.
- Butyl Rubber (Isobutylene-isoprene copolymer) - Impervious gloves in accordance with standard EN374 - Made under licence of European Label System® MSDS software from InfoDyne - http://www.infodyne.fr - SAFETY DATA SHEET (REGULATION (EC) No 1907/2006 - REACH) - Body protection
In the event of substantial spatter, wear liquid-tight protective clothing against chemical risks (type 3) in accordance with EN14605 to prevent skin contact.
In the event of a risk of splashing, wear protective clothing against chemical risks (type 6) in accordance with EN13034 to prevent skin contact.
Work clothing worn by personnel shall be laundered regularly.
After contact with the product, all parts of the body that have been soiled must be washed.
- Respiratory protection
If the ventilation is insufficient, wear appropriate breathing apparatus.
When workers are confronted with concentrations that are above occupational exposure limits, they must wear a suitable, approved, respiratory protection device.
Anti-gas and vapour filter(s) (Combined filters) in accordance with standard EN14387: SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
General information:
Important health, safety and environmental information:
The pH is impossible to measure or its value is not relevant.
Decomposition point/decomposition range : 9.2. Other information
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity
10.2. Chemical stability
This mixture is stable under the recommended handling and storage conditions in section 7.
10.3. Possibility of hazardous reactions
10.4. Conditions to avoid
Any apparatus likely to produce a flame or to have a metallic surface at high temperature (burners, electric arcs, furnaces etc.) must not be allowed on the premises.
- accumulation of electrostatic charges.
- Made under licence of European Label System® MSDS software from InfoDyne - http://www.infodyne.fr - SAFETY DATA SHEET (REGULATION (EC) No 1907/2006 - REACH) 10.5. Incompatible materials
10.6. Hazardous decomposition products
The thermal decomposition may release/form: SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
Repeated or prolonged contact with the mixture may cause removal of natural oil from the skin resulting in non-allergic contact dermatitis and absorption through the skin.
Narcotic effects may occur, such as drowsiness, narcosis, decreased alertness, loss of reflexes, lack of coordination or dizziness.
Effects may also occur in the form of violent headaches or nausea, judgement disorder, giddiness, irritability, fatigue or memory disturbance.
May cause an allergic reaction by skin contact.
Acute toxicity:
No toxicological data available for the mixture.
Acute toxicity:
Trials show that their are no risk for human and children Acute toxicity Inhalation: mg/l skin: 2g/kg rabbit.
eyes not use near or into eyes Ingestion: ml/kg Monograph(s) from the IARC (International Agency for Research on Cancer):
CAS 52645-53-1 : IARC Group 3: The agent is not classifiable as to its carcinogenicity to humans.
SECTION 12: ECOLOGICAL INFORMATION
Very toxic to aquatic life with long lasting effects.
The product must not be allowed to run into drains or waterways.
12.1. Toxicity
Substances
No aquatic toxicity data available for the substances.
Mixtures
No aquatic toxicity data available for the mixture.
12.2. Persistence and degradability
12.3. Bioaccumulative potential
12.4. Mobility in soil
12.5. Results of PBT and vPvB assessment
- Made under licence of European Label System® MSDS software from InfoDyne - http://www.infodyne.fr - SAFETY DATA SHEET (REGULATION (EC) No 1907/2006 - REACH) 12.6. Other adverse effects
SECTION 13: DISPOSAL CONSIDERATIONS
Proper waste management of the mixture and/or its container must be determined in accordance with Directive 2008/98/EC.
13.1. Waste treatment methods
Do not pour into drains or waterways.
Waste management is carried out without endangering human health, without harming the environment and, in particular without risk to water, air, soil, plants or animals.
Recycle or dispose of waste in compliance with current legislation, preferably via a certified collector or company.
Do not contaminate the ground or water with waste, do not dispose of waste into the environment.
Soiled packaging:
Empty container completely. Keep label(s) on container.
Give to a certified disposal contractor.
SECTION 14: TRANSPORT INFORMATION
Transport product in compliance with provisions of the ADR for road, RID for rail, IMDG for sea and ICAO/IATA for air transport (ADR 2011 - IMDG 2010 - ICAO/IATA 2011).
UN1992=FLAMMABLE LIQUID, TOXIC, N.O.S.
SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or
mixture
- Particular provisions:
15.2. Chemical safety assessment
- Made under licence of European Label System® MSDS software from InfoDyne - http://www.infodyne.fr - SAFETY DATA SHEET (REGULATION (EC) No 1907/2006 - REACH) SECTION 16: OTHER INFORMATION
Since the user's working conditions are not known by us, the information supplied on this safety data sheet is based on our current level of knowledge and on national and community regulations.
The mixture must not be used for other uses than those specified in section 1 without having first obtained written handling instructions.
It is at all times the responsibility of the user to take all necessary measures to comply with legal requirements and local regulations.
The information in this safety data sheet must be regarded as a description of the safety requirements relating to the mixture and not as a guarantee of the properties thereof.
Title for H, EUH and R indications mentioned in section 3:
May cause an allergic skin reaction.
Very toxic to aquatic life with long lasting effects.
Harmful by inhalation and if swallowed.
Irritating to respiratory system and skin.
May cause sensitisation by skin contact.
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Vapours may cause drowsiness and dizziness.
Abbreviations:
ADR: European agreement concerning the international carriage of dangerous goods by Road.
IMDG: International Maritime Dangerous Goods.
IATA: International Air Transport Association.
ICAO: International Civil Aviation Organisation RID: Regulations concerning the International carriage of Dangerous goods by rail.
WGK: Wassergefahrdungsklasse (Water Hazard Class).
- Made under licence of European Label System® MSDS software from InfoDyne - http://www.infodyne.fr -

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