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Material Safety Data Sheet
Flammability
Flammability
Instability
Physical hazards
Suggested PPE
1 . Product and Company Identification
Product name
5113600, 5113700 Dragnet FT Emulsifable Insecticide
MSDS prepared by the
4/11/2013.
Environment, Health & Safety
Department on:
Material uses
Product Code
In Case of Emergency
MSDS Number
Transportation: 1-800-792-8311
Medical: 1-877-615-0015
Manufacturer
For more information on Agrium AT or our products, http://www.agriumat.comor contact us at Toll-Free:800-461-6471 2 . Hazards Identification
Physical state
OSHA/HCS status
This material is considered hazardous by the OSHA Hazard Communication Emergency overview
Harmful if swallowed. Do not breathe vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Highly toxic to fish and Potential acute health effects
Inhalation
May irritate the respiratory tract if inhaled. Harmful by inhalation.
Ingestion
Potential chronic health effects
Chronic effects
No known significant effects or critical hazards.
Carcinogenicity
No known significant effects or critical hazards.
Mutagenicity
No known significant effects or critical hazards.
Teratogenicity
No known significant effects or critical hazards.
Developmental effects
No known significant effects or critical hazards.
Fertility effects
No known significant effects or critical hazards.
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2 . Hazards Identification
Over-exposure signs/symptoms
Inhalation
Ingestion
Medical conditions
aggravated by over-
exposure
See toxicological information (Section 11)
3 . Composition / Information on Ingredients
United States
CAS number
CAS number
Classification
CAS number UN number
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
First Aid Measures
Eye contact
Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical Skin contact
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention if irritation develops. Wash thoroughly with soap and water after handling.
Inhalation
If inhalation occurs, remove individual(s) to fresh air. Loosen restrictive clothing items if necessary. If individual has irregular or difficulty breathing or is under respiratory arrest seek medical attention immediately. If other conditions or symptoms develop contact a Ingestion
If ingestion occurs, rinse mouth with copious amounts of water. Do Not induce vomiting unless directedto do so by trained medical personnel. Do Not give anything by mouth to unconcious individuals. Seek immediate medical attention.
Protection of first-
No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water Page: 2/11
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First Aid Measures
Notes to physician
No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Fire-fighting Measures
Flammability of the
In a fire or if heated, a pressure increase will occur and the container may burst.
Extinguishing media
Suitable
Use an extinguishing agent suitable for the surrounding fire.
Not suitable
Special exposure
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable Hazardous thermal
Decomposition products may include the following materials: decomposition products
Special protective
Fire-fighters should wear appropriate protective equipment and self-contained equipment for fire-
breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
fighters
Accidental Release Measures
Personal precautions
No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Do not breathe vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8).
Environmental
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains precautions
and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Methods for cleaning up
Small spill
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste Large spill
Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas.
Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Dispose of via a licensed waste disposal contractor.
Contaminated absorbent material may pose the same hazard as the spilled product.
Note: see section 1 for emergency contact information and section 13 for waste Page: 3/11
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Handling and Storage
Handling
Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist.
Do not ingest. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.
Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Keep out of reach of children.
Exposure Controls / Personal Protection
Occupational exposure limits
TWA (8 hours)
STEL (15 mins)
Ingredient
List name
Notations
Consult local authorities for acceptable exposure limits.
Recommended
If this product contains ingredients with exposure limits, personal, workplace monitoring procedures
atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory Engineering measures
No special ventilation requirements. Good general ventilation should be sufficient to control worker exposure to airborne contaminants. If this product contains ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory Hygiene measures
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Personal protection
Respiratory
Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before Page: 4/11
5113600, 5113700 Dragnet FT Emulsifable Insecticide
Exposure Controls / Personal Protection
Personal protective
equipment
(Pictograms)
Environmental exposure
Emissions from ventilation or work process equipment should be checked to ensure controls
they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Physical and Chemical Properties
Physical state
10 . Stability and Reactivity
Chemical stability
Possibility of hazardous
Under normal conditions of storage and use, hazardous reactions will not occur.
reactions
Hazardous
Under normal conditions of storage and use, hazardous polymerization will not occur.
polymerization
Conditions to avoid
Materials to avoid
Hazardous
Under normal conditions of storage and use, hazardous decomposition products decomposition products
Conditions of reactivity
Highly flammable in the presence of the following materials or conditions: oxidizing 11 . Toxicological Information
United States
Acute toxicity
Product/ingredient name
Exposure
Classification
Product/ingredient name
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11 . Toxicological Information
Acute toxicity
Product/ingredient name
Exposure
Classification
Product/ingredient name
Acute toxicity
Product/ingredient name
Exposure
Classification
Product/ingredient name
12 . Ecological Information
Environmental effects
No known significant effects or critical hazards.
United States
Aquatic ecotoxicity
Product/ingredient name
Exposure
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12 . Ecological Information
Canada
Aquatic ecotoxicity
Product/ingredient name
Exposure
Aquatic ecotoxicity
Product/ingredient name
Exposure
13 . Disposal Considerations
Waste disposal
The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL
PROTECTION for additional handling information and protection of employees.
14 . Transport Information
Regulatory
Shipping name
Additional
information
information
Classification
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14 . Transport Information
TDG
Classification
Classification
15 . Regulatory Information
United States
HCS Classification
U.S. Federal regulations
TSCA 8(a) IUR Exempt/Partial exemption: Partial exemption
United States inventory (TSCA 8b): Not determined.
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: permethrin (ISO)
SARA 311/312 MSDS distribution - chemical inventory - hazard identification:
permethrin (ISO): Immediate (acute) health hazard, Delayed (chronic) health hazard
Clean Air Act (CAA) 112 accidental release prevention: No products were found.
Clean Air Act Section
112(b) Hazardous Air
Pollutants (HAPs)
Clean Air Act Section 602
Class I Substances
Clean Air Act Section 602
Class II Substances
DEA List I Chemicals
(Precursor Chemicals)
DEA List II Chemicals
(Essential Chemicals)
Product name
CAS number
Concentration
Form R - Reporting
requirements
Supplier notification
SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.
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15 . Regulatory Information
State regulations
Connecticut Carcinogen Reporting: None of the components are listed.
Connecticut Hazardous Material Survey: None of the components are listed.
Florida substances: None of the components are listed.
Illinois Chemical Safety Act: None of the components are listed.
Illinois Toxic Substances Disclosure to Employee Act: None of the components
are listed.
Louisiana Reporting: None of the components are listed.
Louisiana Spill: None of the components are listed.
Massachusetts Spill: None of the components are listed.
Massachusetts Substances: The following components are listed: PERMETHRIN
Michigan Critical Material: None of the components are listed.
Minnesota Hazardous Substances: None of the components are listed.
New Jersey Hazardous Substances: None of the components are listed.
New Jersey Spill: None of the components are listed.
New Jersey Toxic Catastrophe Prevention Act: None of the components are listed.
New York Acutely Hazardous Substances: None of the components are listed.
New York Toxic Chemical Release Reporting: None of the components are listed.
Pennsylvania RTK Hazardous Substances: None of the components are listed.
Rhode Island Hazardous Substances: None of the components are listed.
United States inventory
(TSCA 8b)
WHMIS (Canada)
Class D-1B: Material causing immediate and serious toxic effects (Toxic).
Canadian lists
CEPA Toxic substances: None of the components are listed.
Canadian ARET: None of the components are listed.
Canadian NPRI: None of the components are listed.
Alberta Designated Substances: None of the components are listed.
Ontario Designated Substances: None of the components are listed.
Quebec Designated Substances: None of the components are listed.
Canada inventory
This product has been classified in accordance with the hazard criteria of the Controlled Products
Regulations and the MSDS contains all the information required by the Controlled Products Regulations.
Classification
Flammability
Reactivity
EU regulations
Hazard symbol or
symbols
Risk phrases
R20/22- Harmful by inhalation and if swallowed.
R43- May cause sensitization by skin contact.
R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the Page: 9/11
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15 . Regulatory Information
Safety phrases
S2- Keep out of the reach of children.
S46- If swallowed, seek medical advice immediately and show this container or label.
S61- Avoid release to the environment. Refer to special instructions/safety data sheet.
International regulations
International lists
Australia inventory (AICS): All components are listed or exempted.
China inventory (IECSC): All components are listed or exempted.
Japan inventory: All components are listed or exempted.
Korea inventory: All components are listed or exempted.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Chemical Weapons
Convention List
Schedule I Chemicals
Chemical Weapons
Convention List
Schedule II Chemicals
Chemical Weapons
Convention List
Schedule III Chemicals
16 . Other information
Label requirements
Hazardous Material
Information System
(U.S.A.)
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant
hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer may choose to provide them.
HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings
Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material. Suggested protective clothing might not be adequate.
Consult a specialist before handling this product.
National Fire Protection
Association (U.S.A.)
Flammability
Instability
Date of issue
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16 . Other information
Indicates information that has changed from previously issued version.
Notice to Reader:
The buyer assumes all risk in connection with the use of this material. The buyer assumes all responsibility
for ensuring this material is used in a safe manner in compliance with applicable environmental, health and
safety laws, policies and guidelines. Agrium Inc. assumes no responsibility or liability for the information
supplied on this sheet, including any damages or injury caused thereby. Agrium Inc. does not warrant the
fitness of this material for any particular use and assumes no responsibility for injury or damage caused
directly or indirectly by or related to the use of the material. The information contained in this sheet is
developed from what Agrium Inc. believes to be accurate and reliable sources, and is based on the opinions
and facts available on the date of preparation.
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