List of Publications
242. S. Penkov, A. Ogawa, U. Schmidt, D. Tate, V. Zagoriy, S. Boland, M. Gruner, D. Vorkel, J.-M.
Verbavatz, R. J. Sommer, H.-J. Knölker, T. V. Kurzchalia, Nature Chem. Biol.2014, 10, DOI:
10.1038/NCHEMBIO.1460: A Wax Ester Promotes Collective Host Finding in the Nematode
241. A. Kunfermann, M. Witschel, B. Illarionov, R. Martin, M. Rottmann, H. W. Höffken, M. Seet, W.
Eisenreich, H.-J. Knölker, M. Fischer, A. Bacher, M. Groll, F. Diederich, Angew. Chem.2014, 126,
2267–2272; Angew. Chem. Int. Ed.2014, 53, 2235–2239: Pseudilins: Halogenated, Allosteric
Inhibitors of the Non-Mevalonate Pathway Enzyme IspD.
240. C. Thomas, O. Kataeva, A. W. Schmidt, H.-J. Knölker, Org. Biomol. Chem.2014, 12, 872–875:
Transition Metals in Organic Synthesis, Part 112. Regioselective Prenylation of Bromocarbazoles
by Palladium(0)-Catalysed Cross Coupling – Synthesis of O-Methylsiamenol, O-Methylmicro-
239. I. Bauer, H.-J. Knölker in The Chemistry of Organoiron Compounds – PATAI’s Chemistry of Functional Groups; I. Marek, Z. Rappoport, Eds.; Wiley, Chichester, 2014; chap. 5, pp. 155–231:
The Chemistry of Diene–Iron and Dienyl–Iron Complexes.
238. P. Gupta, N. C. Gauthier, Y. Cheng-Han, Y. Zuanning, B. Pontes, M. Ohmstede, R. Martin, H.-J.
Knölker, H.-G. Döbereiner, M. Krendel, M. Sheetz, Biology Open2013, 2, 1288–1299: Myosin 1E
Localizes to Actin Polymerization Sites in Lamellipodia, Affecting Actin Dynamics and Adhesion
237. A. W. Schmidt, T. A. Choi, G. Theumer, S. G. Franzblau, H.-J. Knölker, Bioorg. Med. Chem. Lett.2013, 23, 6111–6113: Inhibitory Effect of Oxygenated Cholestan-3-ol Derivatives on the Growth
236. V. P. Kumar, K. K. Gruner, O. Kataeva, H.-J. Knölker, Angew. Chem.2013, 125, 11279–11283; Angew. Chem. Int. Ed.2013, 52, 11073–11077: Transition Metals in Organic Synthesis, Part 110.
Total Synthesis of the Biscarbazole Alkaloids Murrafoline A–D by a Domino Sonogashira
Coupling/Claisen Rearrangement/Electrocyclization Reaction.
235. R. Hesse, K. K. Gruner, O. Kataeva, A. W. Schmidt, H.-J. Knölker, Chem. Eur. J.2013, 19, 14098–
14111: Transition Metals in Organic Synthesis, Part 109. Efficient Construction of Pyrano[3,2-
a]carbazoles: Application to a Biomimetic Total Synthesis of Cyclized Monoterpenoid Pyrano[3,2-
234. A. Berndt, M. Gruner, A. W. Schmidt, H.-J. Knölker, Synlett2013, 24, 2102–2106: Transition
Metals in Organic Synthesis, Part 111. First Total Synthesis and Structural Revision of Antipathine
233. U. Haußmann, O. Jahn, P. Linning, C. Janßen, T. Liepold, E. Portelius, H. Zetterberg, C. Bauer, J.
Schuchhardt, H.-J. Knölker, H. Klafki, J. Wiltfang, Anal. Chem.2013, 85, 8142–8149: Analysis of
Amino-terminal Variants of Amyloid- Peptides by Capillary Isoelectric Focusing Immunoassay.
232. F. Liu, C.-X. He, L.-J. Luo, Q.-L. Zou, Y.-X. Zhao, R. Saini, S.-F. Han, H.-J. Knölker, L.-S. Wang,
B.-X. Ge, PLOS Pathog.2013, 9, e1003545: Nuclear Hormone Receptor Regulation of MicroRNAs
Controls Innate Immune Responses in C. elegans.
231. S. Agarwal, C. Schroeder, G. Schlechtingen, T. Braxmeier, G. Jennings, H.-J. Knölker, Bioorg. Med. Chem. Lett.2013, 23, 5165–5169: Evaluation of Steroidal Amines as Lipid Raft Modulators
230. R. Saini, O. Kataeva, A. W. Schmidt, Y. Wang, A. Meljon, W. J. Griffiths, H.-J. Knölker, Bioorg. Med. Chem.2013, 21, 5794–5798: Synthesis and Biological Activity of (24E)- and (24Z)-26-
229. H.-J. Knölker in Organometallics in Synthesis – Third Manual; M. Schlosser, Ed.; Wiley, Hoboken,
2013; chap. 4, pp. 545–776: Organoiron Chemistry.
228. C. Hauler, R. Martin, H.-J. Knölker, C. Gaus, J. F. Mueller, W. Vetter, Environ. Poll.2013, 178,
329–335: Discovery and Widespread Occurrence of Polyhalogenated 1,1'-Dimethyl-2,2'-bipyrroles
227. C. Thomas, H.-J. Knölker, Tetrahedron Lett.2013, 54, 591–593: Transition Metals in Organic
Synthesis, Part 108. First Total Synthesis of Ekeberginine.
226. S. Agarwal, O. Kataeva, U. Schmidt, H.-J. Knölker, RSC Adv.2013, 3, 1089–1096: Transition
Metals in Organic Synthesis, Part 107. Silver(I)-Promoted Oxidative Cyclization to Pyrrolo[2,1-
a]isoquinolines and Application to the Synthesis of (±)-Crispine A.
225. M. P. Krahl, O. Kataeva, A. W. Schmidt, H.-J. Knölker, Eur. J. Org. Chem.2013, 59–64:
Transition Metals in Organic Synthesis, Part 106. Iron-Mediated Total Synthesis of 2,7-
224. S. Agarwal, U. Pässler, H.-J. Knölker, Arkivoc2013, (ii), 6–12: Transition Metals in Organic
Synthesis, Part 105. Synthesis of Pyrroles by Silver(I)-Promoted Oxidative Cyclization.
223. M. P. Krahl, A. W. Schmidt, H.-J. Knölker, Heterocycles2012, 86, 357–370: Transition Metals in
Organic Synthesis, Part 104. Iron-Mediated Total Synthesis of Furoclausine-A.
222. G. Schlechtingen, H.-J. Knölker, T. Friedrichson, G. Jennings, T. Braxmeier, PCT WO
2012/160188, 29.11.2012 (Int. Appl. PCT/EP2012/059813, 25.05.2012): Hydroxy-Substituted
Amino and Ammonium Derivatives and their Medical Use.
221. G. Schlechtingen, H.-J. Knölker, T. Friedrichson, G. Jennings, T. Braxmeier, PCT WO
2012/160187, 29.11.2012 (Int. Appl. PCT/EP2012/059812, 25.05.2012): Amino- or Ammonium-
Containing Sulfonic Acid, Phosphonic Acid and Carboxylic Acid Derivatives and their Medical
220. G. Schlechtingen, H.-J. Knölker, T. Friedrichson, G. Jennings, T. Braxmeier, PCT WO
2012/160186, 29.11.2012 (Int. Appl. PCT/EP2012/059810, 25.05.2012): Oxygenated Amino- or
Ammonium-Containing Sulfonic Acid, Phosphonic Acid and Carboxylic Acid Derivatives and their
219. A. Meljon, S. Theofilopoulos, C. H. L. Shackleton, G. L. Watson, N. B. Javitt, H.-J. Knölker, R.
Saini, E. Arenas, Y. Wang, W. J. Griffiths, J. Lipid Res.2012, 53, 2469–2483: Analysis of
Bioactive Oxysterols in Newborn Mouse Brain by LC/MS.
218. P. Linning, U. Haussmann, I. Beyer, S. Weidlich, H. Schieb, J. Wiltfang, H.-W. Klafki, H.-J.
Knölker, Org. Biomol. Chem.2012, 10, 8216–8235: Optimization of BACE1 Inhibition of
Tripartite Structures by Modification of Membrane Anchors, Spacers and Pharmacophores –
Development of Potential Agents for the Treatment of Alzheimer’s Disease.
217. C. Börger, O. Kataeva, H.-J. Knölker, Org. Biomol. Chem.2012, 10, 7269–7273: Transition Metals
in Organic Synthesis, Part 103. Novel Approach to Biscarbazole Alkaloids via Ullmann Coupling –
Synthesis of Murrastifoline-A and Bismurrayafoline-A.
216. C. Börger, H.-J. Knölker, Tetrahedron2012, 68, 6727–6736: Transition Metals in Organic
Synthesis, Part 101. Convergent Total Synthesis of 1,6-Dioxygenated Carbazole Alkaloids.
215. C. Börger, M. P. Krahl, M. Gruner, O. Kataeva, H.-J. Knölker, Org. Biomol. Chem.2012, 10,
5189–5193: Transition Metals in Organic Synthesis, Part 102. First Total Synthesis of the
Biscarbazole Alkaloid Oxydimurrayafoline.
214. A. W. Schmidt, K. R. Reddy, H.-J. Knölker, Chem. Rev.2012, 112, 3193–3328: Occurrence,
Biogenesis, and Synthesis of Biologically Active Carbazole Alkaloids.
213. G. Rouillé, M. Steglich, Y. Carpentier, C. Jäger, F. Huisken, T. Henning, R. Czerwonka, G.
Theumer, C. Börger, I. Bauer, H.-J. Knölker, Astrophys. J.2012, 752, 25: On the Relevance of
Polyynyl-Substituted PAHs to Astrophysics.
212. R. Saini, S. Boland, O. Kataeva, A. W. Schmidt, T. V. Kurzchalia, H.-J. Knölker, Org. Biomol. Chem.2012, 10, 4159–4163: Stereoselective Synthesis and Hormonal Activity of Novel
Dafachronic Acids and Naturally Occurring Steroids Isolated from Corals.
211. L. Huet, R. Forke, A. Jäger, H.-J. Knölker, Synlett2012, 23, 1230–1234: Transition Metals in
Organic Synthesis, Part 100. Highly Efficient Palladium(II)-Catalyzed Oxidative Cyclization to the
1,7,8-Trioxygenated Carbazole Alkaloid Murrayastine.
210. W. Fröhner, K. R. Reddy, H.-J. Knölker, Arkivoc2012, (iii), 330–342: Transition Metals in Organic
Synthesis, Part 98. Transition Metal Mediated Total Synthesis of the Potent Neuronal Cell
Protecting Alkaloid ()-Lavanduquinocin.
209. T. Gensch, M. Rönnefahrt, R. Czerwonka, A. Jäger, O. Kataeva, I. Bauer, H.-J. Knölker, Chem. Eur. J.2012, 18, 770–776: Transition Metals in Organic Synthesis, Part 99. Snapshot of the
Palladium(II)-Catalyzed Oxidative Biaryl Bond Formation by X-Ray Analysis of the Intermediate
208. I. Bauer, H.-J. Knölker, Top. Curr. Chem.2012, 309, 203–253: Synthesis of Pyrrole and Carbazole
207. U. Pässler, H.-J. Knölker in The Alkaloids; H.-J. Knölker, Ed.; Academic Press, London, 2011; Vol.
70, chap. 2, pp. 79–151: The Pyrrolo[2,1-a]isoquinoline Alkaloids.
206. R. Martin, A. Jäger, H.-J. Knölker, Synlett2011, 2795–2798: Transition Metals in Organic
Synthesis, Part 97. Silver-Catalyzed Synthesis of Hexahalogenated 2,2'-Bipyrroles.
205. C. Thomas, O. Kataeva, H.-J. Knölker, Synlett2011, 2663–2666: Transition Metals in Organic
Synthesis, Part 96. First Total Synthesis of Streptoverticillin: Unambiguous Confirmation of the
204. U. Pässler, M. Gruner, S. Penkov, T. V. Kurzchalia, H.-J. Knölker, Synlett2011, 2482–2486:
Synthesis of Ten Members of the Maradolipid Family: Novel Diacyltrehalose Glycolipids from
203. M. Fuchsenberger, R. Forke, H.-J. Knölker, Synlett2011, 2056–2058: Transition Metals in Organic
Synthesis, Part 95. First Total Synthesis of the 1,7-Dioxygenated Carbazole Alkaloids Clausine Q
202. K. Chinthalapudi, M. H. Taft, R. Martin, S. M. Heissler, M. Preller, F. K. Hartmann, H.
Brandstaetter, J. Kendrick-Jones, G. Tsiavaliaris, H. O. Gutzeit, R. Fedorov, F. Buss, H.-J. Knölker,
L. M. Coluccio, D. J. Manstein, J. Biol. Chem.2011, 286, 29700–29708: Mechanism and
Specificity of Pentachloropseudilin-Mediated Inhibition of Myosin Motor Activity.
201. D. Hochbaum, Y. Zhang, C. Stuckenholz, P. Labhart, V. Alexiadis, R. Martin, H.-J. Knölker, A. L.
Fisher, PLoS Genetics2011, 7, e1002179: DAF-12 Regulates a Connected Network of Genes to
200. G. Rouillé, M. Steglich, C. Jäger, F. Huisken, T. Henning, G. Theumer, I. Bauer, H.-J. Knölker,
ChemPhysChem2011, 12, 2131–2137: Spectroscopy of Dibenzorubicene: Experimental Data for a
199. K. K. Gruner, H.-J. Knölker in Heterocycles in Natural Product Synthesis; K. C. Majumdar, S. K.
Chattopadhyay, Eds.; Wiley-VCH, Weinheim, 2011; chap. 10, pp. 341–376: Carbazoles and
198. M. Preller, K. Chinthalapudi, R. Martin, H.-J. Knölker, D. J. Manstein, J. Med. Chem.2011, 54,
3675–3685: Inhibition of Myosin ATPase Activity by Halogenated Pseudilins: A Structure–
197. K. K. Gruner, T. Hopfmann, K. Matsumoto, A. Jäger, T. Katsuki, H.-J. Knölker, Org. Biomol. Chem.2011, 9, 2057–2061: Transition Metals in Organic Synthesis, Part 94. Efficient Iron-
Mediated Approach to Pyrano[3,2-a]carbazole Alkaloids – First Total Synthesis of O-Methylmurra-
yamine A and 7-Methoxymurrayacine, First Asymmetric Synthesis and Assignment of the Absolute
Configuration of (–)-trans-Dihydroxygirinimbine.
196. H. Schieb, S. Weidlich, G. Schlechtingen, P. Linning, G. Jennings, M. Gruner, J. Wiltfang, H.-W.
Klafki, H.-J. Knölker, Chem. Eur. J.2010, 16, 14412–14423: Structural Design, Solid Phase
Synthesis and Activity of Membrane-Anchored -Secretase Inhibitors on A Generation from
195. T. Kurzchalia, T. Hannich, E. Entchev, H.-J. Knölker, R. Martin, PCT WO 2010/146062,
23.12.2010 (Int. Appl. PCT/EP2010/058408, 15.06.2010): Novel Anti-Helminthic Therapies.
194. S. Penkov, F. Mende, V. Zagoriy, C. Erkut, R. Martin, U. Pässler, K. Schuhmann, D. Schwudke, M.
Gruner, J. Mäntler, T. Reichert-Müller, A. Shevchenko, H.-J. Knölker, T. V. Kurzchalia, Angew. Chem.2010, 122, 9620–9625; Angew. Chem. Int. Ed.2010, 49, 9430–9435: Maradolipids:
Diacyltrehalose Glycolipids Specific to Dauer Larva in Caenorhabditis elegans.
193. R. Forke, K. K. Gruner, K. E. Knott, S. Auschill, S. Agarwal, R. Martin, M. Böhl, S. Richter, G.
Tsiavaliaris, R. Fedorov, D. J. Manstein, H. O. Gutzeit, H.-J. Knölker, Pure Appl. Chem.2010, 82,
1975–1991: Transition Metals in Organic Synthesis, Part 93. Total Synthesis of Biologically Active
192. A. W. Schmidt, H.-J. Knölker, Synlett2010, 2207–2239 (Account): Cycloadditions of Allylsilanes,
Part 22. Stereoselective Synthesis of Cyclopentanes and Cyclobutanes by Lewis Acid Promoted
[3+2] and [2+2] Cycloadditions of Allylsilanes.
191. A. W. Schmidt, T. Olpp, E. Baum, T. Stiffel, H.-J. Knölker, Org. Biomol. Chem.2010, 8, 4562–
4568: Cycloadditions of Allylsilanes, Part 21. Organosilicon-Mediated Total Synthesis of the
Triquinane Sesquiterpenes ()--Isocomene and ()-Isocomene.
190. R. Martin, S. Agarwal, A. Jäger, M. Böhl, S. Richter, G. Tsiavaliaris, R. Fedorov, D. J. Manstein,
H. O. Gutzeit, H.-J. Knölker in The Chemistry and Biological Activity of Synthetic and Natural Compounds – Modern Aspects of Chemistry of Heterocycles; V. G. Kartsev, Ed.; ICSPF Press,
Moscow, 2010; pp. 110–117: Specific Inhibitors of Myosin ATPase via Silver-Catalyzed Synthesis
189. A. R. Fischer, N. T. P. Lan, C. Wiedemann, P. Heide, P. Werner, A. W. Schmidt, G. Theumer, H.-J.
Knölker, J. Chromatogr. A2010, 1217, 2950–2955: Determination of 4-Nonylphenol in Water
Samples Using 4-(2,6-Dimethylhept-3-yl)phenol as New Internal Standard.
188. R. Martin, J. Kirst, S. Weidlich, H. Schieb, G. Schlechtingen, A. Jäger, L. Rajendran, M. Böhl, S.
Richter, R. Fedorov, D. J. Manstein, H. O. Gutzeit, H. Klafki, J. Wiltfang, K. Simons, H.-J.
Knölker, Med. Chem. Res.2010, 19, S23–S26: Biomolecular Chemistry Directed Towards Drug
187. R. Martin, E. V. Entchev, T. V. Kurzchalia, H.-J. Knölker, Org. Biomol. Chem.2010, 8, 739–750
(Perspective Article): Steroid Hormones Controlling the Life Cycle of the Nematode
Caenorhabditis elegans: Stereoselective Synthesis and Biology.
186. L. Rajendran, H.-J. Knölker, K. Simons, Nat. Rev. Drug Disc.2010, 9, 29–42: Subcellular
Targeting Strategies for Drug Design and Delivery.
185. R. Martin, A. Jäger, M. Böhl, S. Richter, R. Fedorov, D. J. Manstein, H. O. Gutzeit, H.-J. Knölker,
Angew. Chem.2009, 121, 8186–8190; Angew. Chem. Int. Ed.2009, 48, 8042–8046: Transition
Metals in Organic Synthesis, Part 92. Total Synthesis of Pentabromo- and Pentachloropseudilin,
and Synthetic Analogues – Allosteric Inhibitors of Myosin ATPase.
184. R. Martin, T. Schäfer, G. Theumer, E. V. Entchev, T. V. Kurzchalia, H.-J. Knölker, Synthesis2009,
3488–3492: Improved Synthesis of an Ascaroside Pheromone Controlling Dauer Larva
Development in Caenorhabditis elegans.
183. I. Bauer, H.-J. Knölker in Science of Synthesis; V. H. Rawal, S. A. Kozmin, Eds.; Thieme, Stuttgart,
2009; Vol. 46, chap. 46.13, pp. 637–668: Synthesis via Metal Complexes of Dienes.
182. M. Schmidt, H.-J. Knölker, Synlett2009, 2421–2424: Transition Metals in Organic Synthesis, Part
91. Palladium-Catalyzed Approach to 2,6-Dioxygenated Carbazole Alkaloids – First Total
Synthesis of the Phytoalexin Carbalexin C.
181. H.-J. Knölker, S. Agarwal, G. Schlechtingen, T. Braxmeier, C. Schroeder, G. Jennings, PCT WO
2009/090063, 23.07.2009 (Int. Appl. PCT/EP2009/000216, 15.01.2009): Steroid Sapogenin,
Androstane and Triterpenoid Sapogenin Derivatives for the Treatment and Prevention of Infectious
180. R. Martin, E. V. Entchev, F. Däbritz, T. V. Kurzchalia, H.-J. Knölker, Eur. J. Org. Chem.2009,
3703–3714: Synthesis and Hormonal Activity of the (25S)-Cholesten-26-oic Acids – Potent
Ligands for the DAF-12 Receptor in Caenorhabditis elegans.
179. J. T. Hannich, E. V. Entchev, F. Mende, H. Boytchev, R. Martin, V. Zagoriy, G. Theumer, I.
Riezmann, H. Riezmann, H.-J. Knölker, T. V. Kurzchalia, Dev. Cell2009, 16, 833–843:
Methylation of the Sterol Nucleus by STRM-1 Regulates Dauer Larva Formation in Caenorhabditis
178. A. W. Schmidt, T. Olpp, S. Schmid, A. Jäger, H.-J. Knölker, Tetrahedron2009, 65, 5484–5490 (in Tetrahedron Symposium-in-Print, Number 143: Recent Advances in Organosilicon Chemistry Directed towards Organic Synthesis; P. Langer, Ed.): Cycloadditions of Allylsilanes – Part 20.
Organosilicon-Mediated Total Synthesis of ()-Cameroonanol.
177. D. Manstein, R. Fedorov, G. Tsiavaliaris, H.-J. Knölker, R. Martin, J. Kirst, H. Gutzeit, M. Böhl,
M. Furch, PCT WO 2009/065600, 28.05.2009 (Int. Appl. PCT/EP2008/009891, 21.11.2008):
Means for Treating Myosin-Related Diseases.
176. R. Martin, R. Saini, I. Bauer, M. Gruner, O. Kataeva, V. Zagoriy, E. V. Entchev, T. V. Kurzchalia,
H.-J. Knölker, Org. Biomol. Chem.2009, 7, 2303–2309: 4-Bromo-5-cholestan-3-ol and Nor-
5-cholestan-3-ol Derivatives – Stereoselective Synthesis and Hormonal Activity in
175. R. Beckert, E. Fanghänel, W. D. Habicher, H.-J. Knölker, P. Metz, K. Schwetlick, Organikum – Organisch-chemisches Grundpraktikum, 23. Auflage; Wiley-VCH, Weinheim, 2009; S. 1–861.
174. K. E. Knott, S. Auschill, A. Jäger, H.-J. Knölker, Chem. Commun.2009, 1467–1469: Transition
Metals in Organic Synthesis, Part 90. First Total Synthesis of the Whole Series of the Antiostatins
173. R. Martin, A. W. Schmidt, G. Theumer, T. Krause, E. V. Entchev, T. V. Kurzchalia, H.-J. Knölker,
Org. Biomol. Chem.2009, 7, 909–920: Synthesis and Biological Activity of the (25R)-Cholesten-
26-oic Acids – Ligands for the Hormonal Receptor DAF-12 in Caenorhabditis elegans.
172. R. Fedorov, M. Böhl, G. Tsiavaliaris, F. K. Hartmann, M. H. Taft, P. Baruch, B. Brenner, R.
Martin, H.-J. Knölker, H. O. Gutzeit, D. J. Manstein, Nat. Struct. Mol. Biol.2009, 16, 80–88: The
Mechanism of Pentabromopseudilin Inhibition of Myosin Motor Activity.
171. H.-J. Knölker, Chem. Lett.2009, 38, 8–13 (Highlight Review): Transition Metals in Organic
Synthesis, Part 89. Synthesis of Biologically Active Carbazole Alkaloids Using Selective Transition
170. R. Martin, F. Däbritz, E. V. Entchev, T. V. Kurzchalia, H.-J. Knölker, Org. Biomol. Chem.2008, 6,
4293–4295: Stereoselective Synthesis of the Hormonally Active (25S)-7-Dafachronic Acid, (25S)-4-Dafachronic Acid, (25S)-Dafachronic Acid, and (25S)-Cholestenoic Acid.
169. K. K. Gruner, H.-J. Knölker, Org. Biomol. Chem.2008, 6, 3902–3904: Transition Metals in
Organic Synthesis, Part 88. Palladium-Catalyzed Total Synthesis of Euchrestifoline Using a One-
Pot Wacker Oxidation and Double Aromatic C–H Bond Activation.
168. G. Rouillé, C. Jäger, M. Steglich, F. Huisken, T. Henning, G. Theumer, I. Bauer, H.-J. Knölker,
ChemPhysChem2008, 9, 2085–2091: IR, Raman, and UV/Vis Spectra of Corannulene for Use in
167. I. Bauer, H.-J. Knölker in Iron Catalysis in Organic Chemistry – Reactions and Applications; B.
Plietker, Ed.; Wiley-VCH, Weinheim, 2008; chap. 1, pp. 1–27: Iron Complexes in Organic
166. D. C. Carrer, A. W. Schmidt, H.-J. Knölker, P. Schwille, Langmuir2008, 24, 8807–8812:
Membrane Domain-Disrupting Effects of 4-Substituted Cholesterol Derivatives.
165. R. Martin, A. W. Schmidt, G. Theumer, T. V. Kurzchalia, H.-J. Knölker, Synlett2008, 1965–1968:
Stereoselective Synthesis of (25R)-Dafachronic Acids and (25R)-Cholestenoic Acid as Potential
Ligands for the DAF-12 Receptor in Caenorhabditis elegans.
164. T. A. Choi, R. Czerwonka, R. Forke, A. Jäger, J. Knöll, M. P. Krahl, T. Krause, K. R. Reddy, S. G.
Franzblau, H.-J. Knölker, Med. Chem. Res.2008, 17, 374–385: Transition Metals in Organic
Synthesis, Part 83. Synthesis and Pharmacological Potential of Carbazoles.
163. R. Forke M. P. Krahl, F. Däbritz, A. Jäger, H.-J. Knölker, Synlett2008, 1870–1876: Transition
Metals in Organic Synthesis, Part 87. A Palladium-Catalyzed Route to 2-Oxygenated and 2,7-
Dioxygenated Carbazole Alkaloids – Total Synthesis of 2-Methoxy-3-methylcarbazole,
Glycosinine, Clausine L, Mukonidine, and Clausine V.
162. R. Forke, A. Jäger, H.-J. Knölker, Org. Biomol. Chem.2008, 6, 2481–2483: Transition Metals in
Organic Synthesis, Part 86. First Total Synthesis of Clausine L and Pityriazole, a Metabolite of the
Human Pathogenic Yeast Malassezia furfur.
161. H.-J. Knölker, Sitzungsberichte der Sächsischen Akademie der Wissenschaften zu Leipzig – Mathematisch-naturwissenschaftliche Klasse, Verlag der Sächsischen Akademie der
Wissenschaften zu Leipzig, 2008, Band 131, Heft 1, S. 1–24: Von der Heilpflanze zu neuen
Medikamenten – Welche Beiträge kann die organische Synthese leisten?
160. H.-J. Knölker, S. Agarwal, G. Schlechtingen, T. Braxmeier, C. Schroeder, PCT WO 2008/068037,
12.06.2008 (Int. Appl. PCT/EP2007/010675, 07.12.2007): Cholesterylamines for the Treatment and
159. C. Börger, H.-J. Knölker, Synlett2008, 1698–1702: Transition Metals in Organic Synthesis, Part
85. A General Approach to 1,6-Dioxygenated Carbazole Alkaloids – First Total Synthesis of
158. H.-J. Knölker, K. R. Reddy in The Alkaloids; G. A. Cordell, Ed.; Academic Press, Amsterdam,
2008; Vol. 65, pp. 1–430: Chemistry and Biology of Carbazole Alkaloids.
157. L. Rajendran, A. Schneider, G. Schlechtingen, S. Weidlich, J. Ries, T. Braxmeier, P. Schwille, J. B.
Schulz, C. Schroeder, M. Simons, G. Jennings, H.-J. Knölker, K. Simons, Science2008, 320, 520–
523: Efficient Inhibition of the Alzheimer’s Disease -Secretase by Membrane Targeting.
156. H.-J. Knölker in Modern Alkaloids – Structure, Isolation, Synthesis and Biology; E. Fattorusso, O.
Taglialatela-Scafati, Eds.; Wiley-VCH, Weinheim, 2008; chap. 15, pp. 475–501: Synthesis of
Alkaloids by Transition Metal-Mediated Oxidative Cyclization.
155. W. Fröhner, K. R. Reddy, H.-J. Knölker, Heterocycles2007, 74, 895–912 (Special Issue Dedicated to Professor Ekkehard Winterfeldt): Transition Metals in Organic Synthesis, Part 84. Application of
Iron- and Nickel-Mediated Coupling Reactions to the Total Synthesis of the Neuronal Cell
Protecting Substance ()-Carquinostatin A.
154. A. W. Schmidt, J. R. Suresh, G. Theumer, H.-J. Knölker, Chem. Lett.2007, 36, 1478–1479:
Cycloadditions of Allylsilanes, Part 19. Synthetic Approach Towards the Sex Pheromone of the
Female Oleander Scale Aspidiotus Nerii.
153. A. W. Schmidt, T. Olpp, E. Baum, T. Stiffel, H.-J. Knölker, Synlett2007, 2371–2374:
Cycloadditions of Allylsilanes, Part 18. Stereoselective Total Synthesis of the Sesquiterpene ()--
152. A. W. Schmidt, T. Olpp, S. Schmid, S. Goutal, A. Jäger, H.-J. Knölker, Synlett2007, 1549–1552:
Cycloadditions of Allylsilanes, Part 17. Stereoselective Total Synthesis of the Sesquiterpene ()-
151. R. Forke, M. P. Krahl, T. Krause, G. Schlechtingen, H.-J. Knölker, Synlett2007, 268–272:
Transition Metals in Organic Synthesis, Part 82. First Total Synthesis of Methyl 6-
methoxycarbazole-3-carboxylate, Glycomaurrol, the Anti-TB Active Micromeline, and the
Furo[2,3-c]carbazole Alkaloid Eustifoline-D.
150. T. A. Choi, R. Czerwonka, J. Knöll, M. P. Krahl, K. R. Reddy, S. G. Franzblau, H.-J. Knölker,
Med. Chem. Res.2006, 15, 28–30: Novel Syntheses and Pharmacological Activity of Carbazole
149. M. P. Krahl, A. Jäger, T. Krause, H.-J. Knölker, Org. Biomol. Chem.2006, 4, 3215–3219:
Transition Metal Complexes in Organic Synthesis, Part 81. First Total Synthesis of the 7-
Oxygenated Carbazole Alkaloids Clauszoline-K, 3-Formyl-7-hydroxycarbazole, Clausine M,
Clausine N and the Anti-HIV Active Siamenol Using a Highly Efficient Palladium-Catalyzed
148. J. Knöll, H.-J. Knölker, Tetrahedron Lett.2006, 47, 6079–6082: Transition Metal Complexes in
Organic Synthesis, Part 80. First Total Synthesis of ()-Epocarbazolin A and Epocarbazolin B, and
Asymmetric Synthesis of (–)-Epocarbazolin A via Shi Epoxidation.
147. T. A. Choi, R. Czerwonka, W. Fröhner, M. P. Krahl, K. R. Reddy, S. G. Franzblau, H.-J. Knölker,
ChemMedChem2006, 1, 812–815: Transition Metal Complexes in Organic Synthesis, Part 79.
Synthesis and Activity of Carbazole Derivatives Against Mycobacterium tuberculosis.
146. A. W. Schmidt, T. Doert, S. Goutal, M. Gruner, F. Mende, T. V. Kurzchalia, H.-J. Knölker, Eur. J. Org. Chem.2006, 3687–3706: Regio- and Stereospecific Synthesis of Cholesterol Derivatives and
their Hormonal Activity in Caenorhabditis elegans.
145. S. Agarwal, S. Filali, W. Fröhner, J. Knöll, M. P. Krahl, K. R. Reddy, H.-J. Knölker in The Chemistry and Biological Activity of Synthetic and Natural Compounds – Nitrogen-Containing Heterocycles; V. G. Kartsev, Ed.; ICSPF Press, Moscow, 2006; Vol. 1, pp. 176–186: Application of
Oxidative Cyclizations to the Synthesis of Bioactive Nitrogen-Containing Heterocycles.
144. J. Knöll, H.-J. Knölker, Synlett2006, 651–653: Transition Metal Complexes in Organic Synthesis,
Part 78. First Total Synthesis and Assignment of the Absolute Configuration of the Neuronal Cell
143. R. Czerwonka, K. R. Reddy, E. Baum, H.-J. Knölker, Chem. Commun.2006, 711–713: Transition
Metal Complexes in Organic Synthesis, Part 77. First Enantioselective Total Synthesis of
Neocarazostatin B, Determination of its Absolute Configuration and Transformation into
142. T. Braxmeier, T. Friedrichson, W. Fröhner, G. Jennings, G. Schlechtingen, C. Schroeder, H.-J.
Knölker, K. Simons, M. Zerial, T. Kurzchalia, PCT WO 2006/002909, 12.01.2006 (Int. Appl.
PCT/EP2005/007033, 29.06.2005): Sphingolipid-Derived Pharmaceutical Compositions.
141. T. Braxmeier, T. Friedrichson, W. Fröhner, G. Jennings, G. Schlechtingen, C. Schroeder, H.-J.
Knölker, K. Simons, M. Zerial, T. Kurzchalia, PCT WO 2006/002908, 12.01.2006 (Int. Appl.
PCT/EP2005/007032, 29.06.2005): Carbazole-Derived Pharmaceutical Compositions.
140. T. Braxmeier, T. Friedrichson, W. Fröhner, G. Jennings, G. Schlechtingen, C. Schroeder, H.-J.
Knölker, K. Simons, M. Zerial, T. Kurzchalia, PCT WO 2006/002907, 12.01.2006 (Int. Appl.
PCT/EP2005/007031, 29.06.2005): Use of Steroid-Derived Pharmaceutical Compositions for
Treating Disorders Relating to Pathological Processes in Lipid Rafts.
139. H.-J. Knölker, K. R. Reddy in Selected Methods for Synthesis and Modification of Heterocycles – The Chemistry and Biological Activity of Natural Indole Systems (Part 1); V. G. Kartsev, Ed.;
ICSPF Press, Moscow, 2005; Vol. 4, pp. 166–181: Total Synthesis of Furocarbazole Alkaloids.
138. T. Braxmeier, T. Friedrichson, W. Fröhner, G. Jennings, M. Munick, G. Schlechtingen, C.
Schroeder, H.-J. Knölker, K. Simons, M. Zerial, T. Kurzchalia, PCT WO 2005/097199, 20.10.2005
(Int. Appl. PCT/EP2005/003740, 08.04.2005): Tripartite Conjugates Containing a Structure
Interacting with Cell Membrane Rafts and Their Use.
137. S. Agarwal, J. Knöll, M. P. Krahl, H.-J. Knölker, Journal of Fudan University (Natural Science)2005, 44, 699–700: Synthesis of Heterocyclic Ring Systems Using Organometallic Reagents.
136. S. Agarwal, S. Cämmerer, S. Filali, W. Fröhner, J. Knöll, M. P. Krahl, K. R. Reddy, H.-J. Knölker,
Curr. Org. Chem.2005, 9, 1601–1614 (Special Issue: Recent Progress in Alkaloid Chemistry; H.-J.
Knölker, Ed.): Transition Metal Complexes in Organic Synthesis, Part 75. Novel Routes to
Pyrroles, Indoles and Carbazoles – Applications in Natural Product Synthesis.
135. O. Kataeva, M. P. Krahl, H.-J. Knölker, Org. Biomol. Chem.2005, 3, 3099–3101: Transition Metal
Complexes in Organic Synthesis, Part 76. First Total Synthesis of the Biologically Active 2,7-
Dioxygenated Tricyclic Carbazole Alkaloids 7-Methoxy-O-methylmukonal, Clausine H
(Clauszoline-C), Clausine K (Clauszoline-J) and Clausine O.
134. H.-J. Knölker, Top. Curr. Chem.2005, 244, 115–148: Occurrence, Biological Activity, and
Convergent Organometallic Synthesis of Carbazole Alkaloids.
133. H.-J. Knölker, S. Agarwal, Tetrahedron Lett.2005, 46, 1173–1175: Total Synthesis of the
Antitumor Active Pyrrolo[2,1-a]isoquinoline Alkaloid ()-Crispine A.
132. H.-J. Knölker, W. Fröhner, R. Heinrich, Synlett2004, 2705–2708: Transition Metal Complexes in
Organic Synthesis, Part 74. Total Synthesis of the Marine Alkaloid 6-Chlorohyellazole.
131. S. Agarwal, H.-J. Knölker, Org. Biomol. Chem.2004, 2, 3060–3062: A Novel Pyrrole Synthesis.
130. V. Matyash, E. V. Entchev, F. Mende, M. Wilsch-Bräuninger, C. Thiele, A. W. Schmidt, H.-J.
Knölker, S. Ward, T. V. Kurzchalia, PLoS Biol.2004, 2, e280: Sterol-Derived Hormone(s) Controls
Entry into Diapause in Caenorhabditis elegans by Consecutive Activation of DAF-12 and DAF-16.
129. W. Fröhner, M. P. Krahl, K. R. Reddy, H.-J. Knölker, Heterocycles2004, 63, 2393–2407:
Transition Metal Complexes in Organic Synthesis, Part 73. Synthetic Routes to Naturally Occurring
128. H.-J. Knölker, Curr. Org. Synth.2004, 1, 309–331: Transition Metal Complexes in Organic
Synthesis, Part 70. Synthesis of Biologically Active Carbazole Alkaloids Using Organometallic
127. H.-J. Knölker in Transition Metals for Organic Synthesis – Building Blocks and Fine Chemicals,
Second Edition; M. Beller, C. Bolm, Eds.; Wiley-VCH, Weinheim, 2004; Vol. 1, chap. 3.11, pp.
126. H.-J. Knölker, E. Baum, M. Kosub, Synlett2004, 1769–1771: Transition Metal Complexes in
Organic Synthesis, Part 72. Iron-Mediated Diastereoselective Spiroannelation of Dimethyl
Aminomalonate to the 2-Azaspiro[4.5]decane Ring System.
125. H.-J. Knölker, S. Agarwal, Synlett2004, 1767–1768: Novel Three-Step Synthesis of ()-Harmicine.
124. H.-J. Knölker, M. P. Krahl, Synlett2004, 528–530: Transition Metal Complexes in Organic
Synthesis, Part 71. First Total Synthesis of Furoclausine A.
123. H.-J. Knölker, S. Filali, Synlett2003, 1752–1754: Transition Metal Complexes in Organic
Synthesis, Part 69. Total Synthesis of the Amaryllidaceae Alkaloids Anhydrolycorinone and
Hippadine Using Iron- and Palladium-Mediated Coupling Reactions.
122. H.-J. Knölker, M. Wolpert, Tetrahedron2003, 59, 5317–5322: Transition Metal Complexes in
Organic Synthesis, Part 68. Iron-Mediated Total Synthesis of Mukonine and Mukonidine by
Oxidative Cyclization with Air as the Oxidizing Agent.
121. H.-J. Knölker, J. Knöll, Chem. Commun.2003, 1170–1171: Transition Metal Complexes in Organic
Synthesis, Part 67. First Total Synthesis of the Neuronal Cell Protecting Carbazole Alkaloid
Carbazomadurin A by Sequential Transition Metal-Catalyzed Reactions.
120. H.-J. Knölker, K. R. Reddy, Heterocycles2003, 60, 1049–1052: Indoloquinones, Part 8.
Palladium(II)-Catalyzed Total Synthesis of Murrayaquinone A, Koeniginequinone A, and
119. H.-J. Knölker, W. Fröhner, K. R. Reddy, Eur. J. Org. Chem.2003, 740–746: Transition Metal
Complexes in Organic Synthesis, Part 66. Iron-Mediated Synthesis of Carbazomycin G and
Carbazomycin H, the First Carbazole-1,4-quinol Alkaloids from Streptoverticillium ehimense.
118. H.-J. Knölker, K. R. Reddy, Chem. Rev.2002, 102, 43034427: Isolation and Synthesis of
Biologically Active Carbazole Alkaloids.
117. H.-J. Knölker, T. Hopfmann, Tetrahedron2002, 58, 8937–8945: Transition Metal Complexes in
Organic Synthesis, Part 65. Iron-Mediated Synthesis of Carazostatin, a Free Radical Scavenger
from Streptomyces chromofuscus, and O-Methylcarazostatin.
116. H.-J. Knölker, W. Fröhner, K. R. Reddy, Synthesis2002, 557–564 (Feature Article):
Indoloquinones, Part 7. Total Synthesis of the Potent Lipid Peroxidation Inhibitor Carbazoquinocin
C by an Intramolecular Palladium-Catalyzed Oxidative Coupling of an Anilino-1,4-benzoquinone.
115. H.-J. Knölker, A. Braier, D. J. Bröcher, S. Cämmerer, W. Fröhner, P. Gonser, H. Hermann, D.
Herzberg, K. R. Reddy, G. Rohde, Pure Appl. Chem.2001, 73, 1075–1086: Transition Metal
Complexes in Organic Synthesis, Part 64. Recent Applications of Tricarbonyliron–Diene
114. H.-J. Knölker, W. Fröhner, Synthesis2000, 2131–2136 (in Special Topic: Alkaloids; E. M. Carreira,
Ed.): Transition Metal Complexes in Organic Synthesis, Part 63. Convergent Iron-Mediated
Syntheses of the Furo[3,2-a]carbazole Alkaloid Furostifoline.
113. H.-J. Knölker, Chem. Rev.2000, 100, 2941–2961 (Special Issue: Organometallics in Organic Synthesis; A. de Meijere, Ed.): Transition Metal Complexes in Organic Synthesis, Part 60. Efficient
Synthesis of Tricarbonyliron-Diene Complexes Development of an Asymmetric Catalytic
112. H.-J. Knölker, K. R. Reddy, Tetrahedron2000, 56, 4733–4737: Transition Metal Complexes in
Organic Synthesis, Part 61. Convergent Synthesis of Indolo[2,3-b]carbazole by an Iron-Mediated
Bidirectional Annulation of Two Indole Rings.
111. H.-J. Knölker, S. Cämmerer, Tetrahedron Lett.2000, 41, 5035–5038: Transition Metal Complexes
in Organic Synthesis, Part 62. Total Synthesis of ()-Demethoxycarbonyldihydrogambirtannine and
Norketoyobyrine by an Iron-Mediated [2+2+1] Cycloaddition.
110. H.-J. Knölker, E. Baum, K. R. Reddy, Chirality2000, 12, 526–528 (Special Issue Dedicated to Professor Ryoji Noyori; M. Kitamura, Ed.): Transition Metal Complexes in Organic Synthesis, Part
59. First Enantioselective Total Synthesis of Lavanduquinocin, a Potent Neuronal Cell Protecting
Substance from Streptomyces viridochromogenes.
109. H.-J. Knölker, B. Ahrens, P. Gonser, M. Heininger, P. G. Jones, Tetrahedron2000, 56, 2259–2271
(in Tetrahedron Symposium-in-Print, Number 77: Transition Metal Organometallics in Organic Synthesis; K. M. Nicholas, Ed.): Transition Metal Complexes in Organic Synthesis, Part 57.
Synthesis of 1-Azabuta-1,3-dienes and Application to Catalytic Complexation of Buta-1,3-dienes
and Cycloalkadienes by the Tricarbonyliron Fragment.
108. H.-J. Knölker, E. Baum, K. R. Reddy, Tetrahedron Lett.2000, 41, 1171–1174: Transition Metal
Complexes in Organic Synthesis, Part 58. First Enantioselective Total Synthesis of the Potent
Neuronal Cell Protecting Substance Carquinostatin A from (R)-Propene Oxide.
107. H.-J. Knölker, E. Baum, H. Goesmann, H. Gössel, K. Hartmann, M. Kosub, U. Locher, T. Sommer,
Angew. Chem. 2000, 112, 797–800; Angew. Chem. Int. Ed.2000, 39, 781–784: Transition Metal
Complexes in Organic Synthesis, Part 56. Iron-Mediated Diastereoselective Spiroannelations with
Vinylogous Urethanes A Novel Access to Spiroannelated Carbo- and Heterocycles.
106. H.-J. Knölker, A. Braier, D. J. Bröcher, P. G. Jones, H. Piotrowski, Tetrahedron Lett.1999, 40,
8075–8078: Transition Metal Complexes in Organic Synthesis, Part 55. Synthesis of Corannulene
via an Iron-Mediated [2+2+1] Cycloaddition.
105. H.-J. Knölker, W. Fröhner, Tetrahedron Lett. 1999, 40, 6915–6918: Transition Metal Complexes in
Organic Synthesis, Part 54. Improved Total Syntheses of the Antibiotic Alkaloids Carbazomycin A
104. H.-J. Knölker, G. Baum, O. Schmitt, G. Wanzl, Chem. Commun. 1999, 1737–1738: Cycloadditions
of Allylsilanes, Part 16. Stereoselective Total Synthesis of ()-Fragranol by TiCl4 Promoted [2+2] Cycloaddition of Allyl-tert-butyldiphenylsilane and Methyl Methacrylate.
103. H.-J. Knölker, E. Baum, R. Graf, P. G. Jones, O. Spieß, Angew. Chem. 1999, 111, 2742–2745; Angew. Chem. Int. Ed.1999, 38, 2583–2585: Cycloadditions of Allylsilanes, Part 15. An
Unprecedented Domino Double Allylsilane [3+2] Cycloaddition/Wagner-Meerwein
Rearrangement/Friedel-Crafts Alkylation/Elimination Reaction Sequence Leading to a Novel
102. H.-J. Knölker, E. Baum, T. Hopfmann, Tetrahedron1999, 55, 10391–10412: Transition Metal
Complexes in Organic Synthesis, Part 53. Iron-Mediated Synthesis of Hyellazole and Isohyellazole.
101. H.-J. Knölker, E. Baum, H. Goesmann, R. Klauss, Angew. Chem. 1999, 111, 2196–2199; Angew. Chem. Int. Ed.1999, 38, 2064–2066: Transition Metal Complexes in Organic Synthesis, Part 51.
Demetalation of Tricarbonyl(cyclopentadienone)iron Complexes Initiated by a Ligand Exchange
Reaction with NaOH X-Ray Analysis of a Complex with Nearly Square-Planar Coordinated
100. H.-J. Knölker, Chem. Soc. Rev. 1999, 28, 151–157: Transition Metal Complexes in Organic
Synthesis, Part 47. Organic Synthesis via Tricarbonyl(4-diene)iron Complexes.
99. H.-J. Knölker, H. Hermann, D. Herzberg, Chem. Commun. 1999, 831–832: Transition Metal
Complexes in Organic Synthesis, Part 52. Photolytic Induction of the Asymmetric Catalytic
Complexation of Prochiral Cyclohexa-1,3-dienes by the Tricarbonyliron Fragment.
98. H.-J. Knölker, K. R. Reddy, Synlett1999, 596–598: Indoloquinones, Part 6. First Palladium-
Mediated Oxidative Cyclization of Arylamino-1,2-benzoquinones to Carbazole-3,4-quinones -
Application to the Total Synthesis of Carbazoquinocin C and ()-Carquinostatin A.
97. H.-J. Knölker, N. Foitzik, O. Schmitt, Tetrahedron Lett. 1999, 40, 3557–3560: Cycloadditions of
Allylsilanes, Part 14. Enantiospecific Synthesis of Bicyclo[4.3.0]nonanes by Asymmetric [3+2]
96. H.-J. Knölker, D. Herzberg, Tetrahedron Lett. 1999, 40, 3547–3548: Transition Metal Complexes
in Organic Synthesis, Part 50. Asymmetric Catalytic Complexation of 1-Methoxycyclohexa-1,3-
diene by the Tricarbonyliron Fragment using Amino Acid-Derived 1-Azabuta-1,3-dienes.
95. H.-J. Knölker, H. Goesmann, H. Hermann, D. Herzberg, G. Rohde, Synlett1999, 421–425:
Transition Metal Complexes in Organic Synthesis, Part 49. Development of Novel Chiral Catalysts
for the Asymmetric Catalytic Complexation of Prochiral Cyclohexa-1,3-dienes by the
Tricarbonyliron Fragment - Mechanism of the Asymmetric Catalysis and Involvement of a
94. H.-J. Knölker, H. Goesmann, R. Klauss, Angew. Chem. 1999, 111, 727–731; Angew. Chem. Int. Ed. 1999, 38, 702–705: Transition Metal Complexes in Organic Synthesis, Part 48. A Novel Method for
the Demetalation of Tricarbonyliron–Diene Complexes by a Photolytically Induced Ligand
93. H.-J. Knölker, N. Foitzik, C. Gabler, R. Graf, Synthesis1999, 145–151: Cycloadditions of
Allylsilanes, Part 12. Regio- and Stereoselective Transformations of Silylbicyclo[n.3.0]alkanes.
92. H.-J. Knölker, T. Braxmeier, Tetrahedron Lett. 1998, 39, 9407–9410: Isocyanates, Part 5. Synthesis
of Oxazolidin-2-ones and Imidazolidin-2-ones via DMAP-Catalyzed Isocyanation of Amines with
91. H.-J. Knölker, K. R. Reddy, A. Wagner, Tetrahedron Lett. 1998, 39, 8267–8270: Indoloquinones,
Part 5. Palladium-Catalyzed Total Synthesis of the Potent Lipid Peroxidation Inhibitor
90. H.-J. Knölker, E. Baum, O. Schmitt, Tetrahedron Lett. 1998, 39, 7705–7708: Cycloadditions of
Allylsilanes, Part 13. Lewis Acid-Promoted Stereospecific [2+2] Cycloaddition of Crotylsilanes and
89. H.-J. Knölker in Transition Metals for Organic Synthesis – Building Blocks and Fine Chemicals;
M. Beller, C. Bolm, Eds.; Wiley-VCH, Weinheim, 1998; Vol. 1, chap. 3.13, pp. 534–549:
88. H.-J. Knölker, E. Baum, P. Gonser, G. Rohde, H. Röttele, Organometallics1998, 17, 3916–3925:
Transition Metal Complexes in Organic Synthesis, Part 45. 1,4-Diaryl-1-azabuta-1,3-diene-
Catalyzed Complexation of Cyclohexa-1,3-diene by the Tricarbonyliron Fragment Development
of Highly Efficient Catalysts, Optimization of the Reaction Conditions, and Proposed Mechanism.
87. H.-J. Knölker, M. Graf, U. Mangei, J. Prakt. Chem. 1998, 340, 530–535: Transition Metal
Complexes in Organic Synthesis, Part 46. Synthesis of 5-Arylmethyl-substituted Tricarbonyl(1-4--cyclohexa-1,3-diene)iron Complexes.
86. H.-J. Knölker, G. Baum, N. Foitzik, H. Goesmann, P. Gonser, P. G. Jones, H. Röttele, Eur. J. Inorg. Chem.1998, 993–1007: Transition Metal Complexes in Organic Synthesis, Part 41. Synthesis,
Molecular Structure, Fluxional Behavior, and Tricarbonyliron Transfer Reactions of (4-1-
Azabuta-1,3-diene)tricarbonyliron Complexes.
85. H.-J. Knölker, K. R. Reddy, Tetrahedron Lett.1998, 39, 4007–4008: Transition Metal Complexes
in Organic Synthesis, Part 44. Iron-Mediated Synthesis of Indolo[2,3-b]carbazole.
84. H.-J. Knölker, P. G. Jones, G. Wanzl, Synlett1998, 613–616: Cycloadditions of Allylsilanes, Part
11. Stereoselective Synthesis of Hydroxycyclopentanes and Hydroxymethylcyclobutanes by
Titanium Tetrachloride Promoted [3+2] and [2+2] Cycloadditions of Sterically Hindered
Allylsilanes and Subsequent Oxidative Cleavage of the Carbon Silicon Bond.
83. H.-J. Knölker, W. Fröhner, A. Wagner, Tetrahedron Lett.1998, 39, 2947: Transition Metal
Complexes in Organic Synthesis, Part 43. First Total Synthesis of the Free Radical Scavenger ()-
Neocarazostatin B via Iron- and Nickel-Mediated Coupling Reactions.
82. H.-J. Knölker, W. Fröhner, Tetrahedron Lett.1998, 39, 2537: Transition Metal Complexes in
Organic Synthesis, Part 42. First Total Synthesis of the Potent Neuronal Cell Protecting Substance
()-Lavanduquinocin via Iron- and Nickel-Mediated Coupling Reactions.
81. H.-J. Knölker, W. Fröhner, J. Chem. Soc. Perkin Trans. 11998, 173–175: Indoloquinones, Part 4.
Palladium-Catalyzed Total Synthesis of the Antibiotic Carbazole Alkaloids Carbazomycin G and H.
80. H.-J. Knölker, E. Baum, M. Heininger, Tetrahedron Lett.1997, 38, 8021–8024: Transition Metal
Complexes in Organic Synthesis, Part 40. Diastereoselective Synthesis of Substituted
Perhydroacenaphthene Derivatives via Intramolecular Diels-Alder Cycloadditions.
79. H.-J. Knölker, T. Braxmeier, H. Oberhammer, J. Mol. Struct. 1997, 413–414, 211–216 (Special Issue: Structural Chemistry): Tert-Butyl Isocyanate, a Non-Rigid Molecule.
78. H.-J. Knölker, W. Fröhner, Synlett1997, 1108: Transition Metal Complexes in Organic Synthesis,
Part 39. First Total Synthesis of the Potent Neuronal Cell Protecting Substance ()-Carquinostatin
A via Iron- and Nickel-Mediated Coupling Reactions.
77. H.-J. Knölker, T. Braxmeier, Synlett1997, 925: Isocyanates, Part 4. Convenient Phosgene-Free
Method for the Synthesis and Derivatization of Enantiopure -Isocyanato Carboxylic Acid Esters.
76. H.-J. Knölker, W. Fröhner, Tetrahedron Lett. 1997, 38, 4051: Transition Metal Complexes in
Organic Synthesis, Part 38. First Total Synthesis of Carbazomycin G and H.
J. Prakt. Chem. 1997, 339, 304–314 (Special Issue Dedicated to Professor Ekkehard Winterfeldt): Cycloadditions of Allylsilanes, Part 10. Stereoselective Construction of Ring Systems
by Cycloaddition Reactions of Allyltriisopropylsilane.
74. H.-J. Knölker, N. Foitzik, H. Goesmann, R. Graf, P. G. Jones, G. Wanzl, Chem. Eur. J.1997, 3,
538–551: Cycloadditions of Allylsilanes, Part 9. Highly Stereoselective Synthesis of
Bicyclo[n.3.0]alkanes by Titanium Tetrachloride Promoted [3+2] Cycloaddition of Allylsilanes and
73. H.-J. Knölker, W. Fröhner, Tetrahedron Lett. 1997, 38, 1535–1538: Transition Metal Complexes in
Organic Synthesis, Part 37. Convergent Iron-Mediated Total Synthesis of the Potent Lipid
Peroxidation Inhibitor Carbazoquinocin C.
72. H.-J. Knölker, G. Schlechtingen, J. Chem. Soc. Perkin Trans. 11997, 349: Transition Metal
Complexes in Organic Synthesis, Part 34. First Total Synthesis of Carbazomycin C and D.
71. H.-J. Knölker, M. Wolpert, Tetrahedron Lett. 1997, 38, 533–536: Transition Metal Complexes in
Organic Synthesis, Part 36. Cyclization of Tricarbonyliron Complexes by Oxygen to 4a,9a-
Dihydro-9H-carbazoles: Application to the Synthesis of Mukonine, Mukonidine, and Pyrido[3,2,1-
70. H.-J. Knölker, T. Braxmeier, G. Schlechtingen, German Patent DE 19526081, 1997 [(Cl.
C07C265/00), 23 Jan 1997, DE Appl. 19526081.3, 18.07.1995]; Chem. Abstr.1997, 126, 172036c:
Verfahren zur Herstellung von sterisch gehinderten organischen Mono- und Polyisocyanaten.
69. H.-J. Knölker, A. Ecker, P. Struwe, A. Steinmeyer, G. Müller, G. Neef, Tetrahedron1997, 53, 91–
108: Enantioselective Synthesis of Calcitriol A-Ring Fragments.
68. H.-J. Knölker, W. Fröhner, Tetrahedron Lett. 1996, 37, 9183: Transition Metal Complexes in
Organic Synthesis, Part 35. First Total Synthesis of Furostifoline.
67. H.-J. Knölker, P. G. Jones, R. Graf, Synlett1996, 1155–1158: Cycloadditions of Allylsilanes, Part
8. Diastereoselective Synthesis of Spirocyclopentanes by Lewis Acid Promoted [3+2]
Cycloaddition of Allyltriisopropylsilane and 2-Alkylidenecycloalkan-1-ones.
66. H.-J. Knölker, C. Hofmann, Tetrahedron Lett. 1996, 37, 7947: Transition Metal Complexes in
Organic Synthesis, Part 33. Molybdenum-Mediated Total Synthesis of Girinimbine, Murrayacine,
65. H.-J. Knölker, H. Goesmann, P. Gonser, Tetrahedron Lett. 1996, 37, 6543: Transition Metal
Complexes in Organic Synthesis, Part 32. Fluxionality of (4-1-Aza-1,3-butadiene)tricarbonyliron
64. H.-J. Knölker, H. Goesmann, C. Hofmann, Synlett1996, 737–740: Transition Metal Complexes in
Organic Synthesis, Part 31. A Novel Molybdenum-Mediated Synthesis of Carbazole Derivatives:
Application to the Total Synthesis of Mukonal and 1,1'-Bis(2-hydroxy-3-methylcarbazole).
63. H.-J. Knölker, T. Braxmeier, Tetrahedron Lett. 1996, 37, 5861: Isocyanates, Part 3. Synthesis of
Carbamates by DMAP-Catalyzed Reaction of Amines with Di-tert-butyldicarbonate and Alcohols.
62. H.-J. Knölker, F. Budei, J.-B. Pannek, G. Schlechtingen, Synlett1996, 587–589: Transition Metal-
Diene Complexes in Organic Synthesis, Part 30. On the Mechanism of the Oxidative Cyclizations
of Tricarbonyl(4-cyclohexadiene)iron Complexes: Unequivocal Determination of the
Regioselectivity and the Stereospecificity of the Cyclization Process by Deuterium Labeling
61. H.-J. Knölker, T. Braxmeier, G. Schlechtingen, Synlett1996, 502: Isocyanates, Part 2. Synthesis of
Symmetrical and Unsymmetrical Ureas by DMAP-Catalyzed Reaction of Alkyl- and Arylamines
60. H.-J. Knölker, G. Baum, J.-B. Pannek, Tetrahedron1996, 52, 7345–7362 (in Tetrahedron Symposium-in-Print, Number 61: New Synthetic Methods-IV. Organometallics in Organic Chemistry; I. E. Markó, Ed.): Transition Metal-Diene Complexes in Organic Synthesis, Part 27.
Synthesis and Reactivity of 4a,9a-Dihydro-9H-carbazoles.
59. H.-J. Knölker, P. Gonser, T. Koegler, Tetrahedron Lett. 1996, 37, 2405: Transition Metal-Diene
Complexes in Organic Synthesis, Part 29. Separation of Planar Chiral Tricarbonyliron-Diene
Complexes at Cyclodextrin Bonded Chiral Stationary Phases by HPLC.
J. Prakt. Chem. 1996, 338, 190–192: The Reagent. Trimethylamine N-oxide A
57. A. Steinmeyer, G. Neef, G. Müller, H.-J. Knölker, German Patent DE 4423669, 1996 [PCT Int.
Appl. WO 9600207 (Cl. C07C69/013), 4 Jan 1996, DE Appl. 4423669, 23.06.1994]; Chem. Abstr.
1996, 124, 202734g: Cyclohexanon-Derivate, Verfahren zu deren Herstellung und
56. H.-J. Knölker, H. Hermann, Angew. Chem. 1996, 108, 363; Angew. Chem. Int. Ed. Engl. 1996, 35,
341: Transition Metal-Diene Complexes in Organic Synthesis, Part 28. Asymmetric Catalysis in the
Complexation of Prochiral Dienes by the Tricarbonyliron Fragment: A Novel Methodology for the
Enantioselective Synthesis of Planar Chiral Tricarbonyl(diene)iron Complexes.
55. H.-J. Knölker, T. Braxmeier, G. Schlechtingen, Angew. Chem. 1995, 107, 2746; Angew. Chem. Int. Ed. Engl. 1995, 34, 2497–2500: A Novel Method for the Synthesis of Isocyanates Under Mild
54. H.-J. Knölker, G. Baum, P. Gonser, Tetrahedron Lett. 1995, 36, 8191–8194: Transition Metal-
Diene Complexes in Organic Synthesis, Part 26. Synthesis of Enantiopure (4-1-Aza-1,3-
53. H.-J. Knölker in Encyclopedia of Reagents for Organic Synthesis; L. A. Paquette, Ed.; Wiley,
Chichester 1995; Vol. 1, p. 333: (4-Benzylideneacetone)tricarbonyliron.
52. H.-J. Knölker, E. Baum, J. Heber, Tetrahedron Lett. 1995, 36, 7647–7650: Transition Metal-Diene
Complexes in Organic Synthesis, Part 25. Cycloadditions of Annulated 2,5-Bistrimethylsilylcyclo-
51. H.-J. Knölker, T. Hopfmann, Synlett1995, 981: Transition Metal-Diene Complexes in Organic
Synthesis, Part 24. Total Synthesis of the Naturally Occurring Free Radical Scavenger Carazostatin.
50. H.-J. Knölker, E. Baum, T. Hopfmann, Tetrahedron Lett.1995, 36, 5339: Transition Metal-Diene
Complexes in Organic Synthesis, Part 23. Total Synthesis of the Marine Alkaloid Hyellazole.
49. H.-J. Knölker, M. Bauermeister, J.-B. Pannek, M. Wolpert, Synthesis1995, 397: Transition Metal-
Diene Complexes in Organic Synthesis, Part 22. The Iron-Mediated Quinone Imine Cylization: A
48. H.-J. Knölker, G. Wanzl, Synlett1995, 378–382: Cycloadditions of Allylsilanes, Part 7.
Stereoselective Synthesis of Hydroxycyclopentanes from Silylcyclopentanes by Oxidative Cleavage
47. H.-J. Knölker in Advances in Nitrogen Heterocycles; C. J. Moody, Ed.; JAI Press, Greenwich (CT),
1995; Vol. 1, pp. 173–204: Transition Metal-Mediated Synthesis of Carbazole Derivatives. J. Prakt. Chem.1995, 337, 75–77: The Reagent. Manganese Dioxide, a Versatile
45. H.-J. Knölker, G. Baum, M. Kosub, Synlett1994, 1012: Transition Metal-Diene Complexes in
Organic Synthesis, Part 21. Iron-Mediated Diastereoselective Cyclizations to 1-Oxaspiro[4.5]-
44. H.-J. Knölker, N. O'Sullivan, Tetrahedron1994, 50, 10893–10908: Indoloquinones, Part 3.
Palladium-Promoted Synthesis of Hydroxy-Substituted 5-Cyano-5H-benzo[b]carbazole-6,11-
43. H.-J. Knölker, G. Baum, R. Graf, Angew. Chem.1994, 106, 1705–1707; Angew. Chem. Int. Ed. Engl.1994, 33, 1612–1615: Cycloadditions of Allylsilanes, Part 6. Lewis Acid Promoted [2+2]
Cycloaddition of Allylsilanes and Unsaturated Esters: A Novel Method for Cyclobutane
42. H.-J. Knölker, P. Gonser, P. G. Jones, Synlett1994, 405–408: Transition Metal-Diene Complexes in
Organic Synthesis, Part 20. Development of Highly Efficient 1-Aza-1,3-butadiene Catalysts for the
Complexation of 1,3-Dienes by the Tricarbonyliron Fragment.
41. H.-J. Knölker, M. Bauermeister, J. Indian Chem. Soc.1994, 71, 345 (Special Issue Dedicated to Professor D. P. Chakraborty): Transition Metal-Diene Complexes in Organic Synthesis, Part 17.
Studies Directed Towards the Iron-Mediated Synthesis of 2-Oxygenated Carbazole Alkaloids.
40. H.-J. Knölker, R. Hitzemann, Tetrahedron Lett.1994, 35, 2157: Imidazole Derivatives, Part IX.
Selective Reactions of Functionalized Imidazo[1,2-a]pyridines: Stereospecific Synthesis of 5,6-
J. Prakt. Chem.1994, 336, 277–279: The Reagent. Pentacarbonyliron Fe[CO]5.
38. H.-J. Knölker, N. O'Sullivan, Tetrahedron Lett.1994, 35, 1695–1698: Indoloquinones, Part 2.
Palladium-Promoted Synthesis of a 7-Deoxyprekinamycin Isomer.
37. H.-J. Knölker, A.-A. El-Ahl, G. Weingärtner, Synlett1994, 194–196: Transition Metal-Diene
Complexes in Organic Synthesis, Part 19. Oxidative Cyclization of Alkylamines at Tricarbonyliron-
Cyclohexadiene Complexes: A Simple Access to Indole Derivatives.
36. H.-J. Knölker, R. Graf, Synlett1994, 131–133: [3+2] Cycloadditions of Allylsilanes, Part 5.
Synthesis of Bicyclo[3.3.0]octanes by Domino [3+2] Cycloadditions of Allylsilanes and 3-Butyn-2-
35. H.-J. Knölker, J. Heber, Synlett1993, 924–926: Transition Metal-Diene Complexes in Organic
Synthesis, Part 18. Iron-Mediated [2+2+1] Cycloadditions of Diynes and Carbon Monoxide:
34. H.-J. Knölker, M. Bauermeister, Tetrahedron1993, 49, 11221–11236: Transition Metal-Diene
Complexes in Organic Synthesis, Part 16. Iron-Mediated Total Synthesis of 1-Oxygenated
33. H.-J. Knölker, N. Foitzik, R. Graf, J.-B. Pannek, P. G. Jones, Tetrahedron1993, 49, 9955–9972:
[3+2] Cycloadditions of Allylsilanes, Part 4. Dual Reactivity of Allyltrimethylsilane: Sakurai
Reaction versus Trimethylsilylcyclopentane Annulation.
32. H.-J. Knölker, M. Bauermeister, Helv. Chim. Acta1993, 76, 2500–2514: Transition Metal-Diene
Complexes in Organic Synthesis, Part 15. Iron-Mediated Total Synthesis of Carbazomycin A and
31. H.-J. Knölker, K. Hartmann, Synlett1993, 755–757: Indoloquinones, Part 1. Synthesis of 4,7-
Dibenzyloxyindole and Selective Transformations to 4,7-Indoloquinones.
30. H.-J. Knölker, R. Graf, Tetrahedron Lett.1993, 34, 4765–4768: [3+2] Cycloadditions of
Allylsilanes, Part 3. Diastereoselective Construction of Two Contiguous Quaternary Carbon
Centers by [3+2] Cycloaddition of Allyltrisisopropylsilane.
29. H.-J. Knölker, N. Foitzik, H. Goesmann, R. Graf, Angew. Chem.1993, 105, 1104–1106; Angew. Chem. Int. Ed. Engl.1993, 32, 1081–1083: [3+2] Cycloadditions of Allylsilanes, Part 2. A Versatile
and Efficient Synthesis of Annulated Cyclopentanes by Stereoselective [3+2] Cycloaddition of
Allylsilanes and Cycloalkenyl Methyl Ketones.
28. H.-J. Knölker, A.-A. El-Ahl, Heterocycles1993, 36, 1381: Imidazole Derivatives, Part VIII.
Stereoselective Formation of 1-[(E) 3-(1-Imidazolyl)-2-alkenoyl]imidazoles.
27. H.-J. Knölker, M. Bauermeister, J.-B. Pannek, D. Bläser, R. Boese, Tetrahedron1993, 49, 841–
862: Transition Metal-Diene Complexes in Organic Synthesis, Part 13. Highly Chemo- and
Stereoselective Oxidations of Tricarbonyliron-Cyclohexadiene Complexes: Synthesis of 4-
26. H.-J. Knölker, J. Heber, C. H. Mahler, Synlett1992, 1002–1004: Transition Metal-Diene
Complexes in Organic Synthesis, Part 14. Regioselective Iron-Mediated [2+2+1] Cycloadditions of
Alkynes and Carbon Monoxide: Synthesis of Substituted Cyclopentadienones.
25. H.-J. Knölker, M. Bauermeister, J.-B. Pannek, Chem. Ber.1992, 125, 2783: Transition Metal-Diene
Complexes in Organic Synthesis, Part 12. Regio- and Stereoselectivity of Electrophilic
Substitutions of Arylamines by Tricarbonyliron-Complexed Cyclohexadienylium Cations and
24. H.-J. Knölker, R. Boese, D. Döring, A.-A. El-Ahl, R. Hitzemann, P. G. Jones, Chem. Ber.1992, 125, 1939–1951: Imidazole Derivatives, VII. Reaction of 1-Acylimidazoles with Dialkyl
Acetylenedicarboxylates: Synthesis of Imidazo[1,2-a]pyridines, 2-Imidazolylmaleates, 1,5-
Dihydroimidazo[1,2-a]pyridines, Furo[2',3':2,3]pyrrolo[1,2-a]imidazoles,
Furo[2',3':2,3]pyrrolo[1,2-a]benzimidazoles, and 7H-Pyrrolo[1,2-a]imidazoles.
23. H.-J. Knölker, P. Gonser, Synlett1992, 517–520: Transition Metal-Diene Complexes in Organic
Synthesis, Part 11. Tricarbonyl(4-1-aza-1,3-butadiene)iron Complexes as Iron Tricarbonyl
Transfer Reagents: 1-Aza-1,3-butadiene-Catalyzed Transfer of the Iron Tricarbonyl Fragment and
Complexation of 1,3-Dienes by Polymer-Supported Iron Tricarbonyl.
Synlett1992, 371–387 (Account): Transition Metal-Diene Complexes in Organic
Synthesis, Part 10. Iron-Mediated Synthesis of Heterocyclic Ring Systems and Applications in
21. H.-J. Knölker, M. Bauermeister, Heterocycles1991, 32, 2443–2450: Transition Metal-Diene
Complexes in Organic Synthesis, Part 9. First Total Synthesis of Carbazomycinal.
20. H.-J. Knölker, K. Hartmann, Synlett1991, 428–430: Transition Metal-Diene Complexes in Organic
Synthesis, Part 8. Iron-Mediated Approach to the Discorhabdin and Prianosin Alkaloids.
19. H.-J. Knölker, R. Boese, K. Hartmann, Tetrahedron Lett.1991, 32, 1953–1956: Transition Metal-
Diene Complexes in Organic Synthesis, Part 7. Regioselectivity Control in Iron-Mediated
Diastereoselective Spiroannelations of Arylamines: Cyclization to 1-Aza- versus 3-
18. H.-J. Knölker, D. Döring, A.-A. El-Ahl, P. G. Jones, Synlett1991, 241: Imidazole Derivatives, Part
VI. A Diastereoselective Spirobicyclization Reaction Leading to the Novel Imidazo[1',2':1,2]-
17. H.-J. Knölker, P. G. Jones, J.-B. Pannek, A. Weinkauf, Synlett1991, 147: Transition Metal-Diene
Complexes in Organic Synthesis, Part 6. Stereoselective Synthesis of Iron-Complexed 4b,8a-
Dihydrocarbazol-3-ones: A Novel Route to 4a,9a-Dihydro-9H-carbazoles and Highly Chemo-,
Regio-, and Stereoselective Sakurai Reactions.
16. H.-J. Knölker in Organic Synthesis via Organometallics; K. H. Dötz, R. W. Hoffmann, Eds.;
Vieweg, Braunschweig 1991, p. 119: Transition Metal-Diene Complexes in Organic Synthesis, Part
5. Applications of Iron-Diene Complexes to Natural Product Synthesis.
15. H.-J. Knölker in 40 Jahre Fonds der Chemischen Industrie 1950-1990; Verband der Chemischen
Industrie, Ed.; Frankfurt 1990, S. 219: Eisen-vermittelte Synthese von Heterocyclen.
14. H.-J. Knölker, R. Boese, R. Hitzemann, Heterocycles1990, 31, 1435: Imidazole Derivatives, Part
V. Imidazo[1',2':1,6]pyrido[2,3-d]pyridazine: Synthesis, Structure, and Preliminary Chemistry of a
13. H.-J. Knölker, P. G. Jones, J.-B. Pannek, Synlett1990, 429–430: Conjugate Addition of Allylsilanes
with Subsequent Sila-Wagner-Meerwein Rearrangement: A Novel Methodology for Stereoselective
12. H.-J. Knölker, R. Boese, J. Chem. Soc. Perkin Trans. 11990, 1821: Imidazole Derivatives, Part 4.
A Novel and Direct Synthesis of 7H-Pyrrolo[1,2-a]imidazoles.
11. H.-J. Knölker, M. Bauermeister, J. Chem. Soc. Chem. Commun. 1990, 664–665: Transition Metal-
Diene Complexes in Organic Synthesis, Part 4. Iron-Mediated Total Synthesis of the Cytotoxic
Carbazole Koenoline and Related Alkaloids.
10. H.-J. Knölker, R. Boese, R. Hitzemann, Chem. Ber.1990, 123, 327: Imidazole Derivatives, III.
Regiospecific Synthesis, Structure and Fluorescence Properties of Highly Substituted Imidazo[1,2-
a]pyridines and Pyrido[1,2-a]benzimidazoles.
9. H.-J. Knölker, R. Boese, K. Hartmann, Angew. Chem.1989, 101, 1745; Angew. Chem. Int. Ed. Engl.1989, 28, 1678–1679: Transition Metal-Diene Complexes in Organic Synthesis, Part 3. Iron-
mediated Diastereoselective Spiroannelation to the Spiro[1,2,3,4-tetrahydroquinoline-4,1'-cyclo-
hexane] System and a Novel Rearrangement to 2,3-Dihydroindole Derivatives.
8. H.-J. Knölker, M. Bauermeister, J. Chem. Soc. Chem. Commun.1989, 1468–1470: Transition
Metal-Diene Complexes in Organic Synthesis, Part 2. The Total Synthesis of the Carbazole
Antibiotic Carbazomycin B and an Improved Route to Carbazomycin A.
7. H.-J. Knölker, R. Boese, R. Hitzemann, Heterocycles1989, 29, 1551: Imidazole Derivatives, Part
II. Synthesis of Imidazo[1,2-a]pyridin-5-ones.
6. H.-J. Knölker, M. Bauermeister, D. Bläser, R. Boese, J.-B. Pannek, Angew. Chem.1989, 101, 225–
227; Angew. Chem. Int. Ed. Engl.1989, 28, 223–225: Transition Metal-Diene Complexes in
Organic Synthesis, Part 1. Highly Selective Oxidations of Fe(CO)3-Cyclohexadiene Complexes: Synthesis of 4b,8a-Dihydrocarbazol-3-ones and the First Total Synthesis of Carbazomycin A.
5. H.-J. Knölker, R. Boese, J. Chem. Soc. Chem. Commun.1988, 1151: A Novel Synthesis of the
Imidazo[1,2-a]pyridine Ring System.
4. R. Boese, H.-J. Knölker, K.P.C. Vollhardt, Angew. Chem.1987, 99, 1067; Angew. Chem. Int. Ed. Engl.1987, 26, 1035: Cobalt-Mediated [2+2+2] Cycloadditions of Alkynes to the Imidazole 4,5-
Double Bond. First Synthesis of the 3a,7a-Dihydrobenzimidazole Nucleus and Its Preliminary
Chemistry Including a Novel Quinoline Construction.
3. P. Hölscher, H.-J. Knölker, E. Winterfeldt, Isr. J. Chem.1991, 31, 187: An Enantioselective Total
Synthesis of (+)-Elenoic Acid and the Non-Natural Enantiomers of Tetrahydroalstonine, Aricine,
2. P. Hölscher, H.-J. Knölker, E. Winterfeldt, Tetrahedron Lett.1990, 31, 2705: Enantioselective
Total Synthesis of (+)-Tetrahydroalstonine, (+)-Aricine, and (+)-Reserpinine.
1. H.-J. Knölker, E. Winterfeldt, Liebigs Ann. Chem.1986, 465: Stereoselective Routes to
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