Autosmart.co.uk

SAFETY DATA SHEET
Compilation date: 24/07/2007
Revision date: 24/02/2012
Revision No: 9
Section 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name: HRED/L HARDENER BPO
Product code: HRED/L
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of substance / mixture: HARDENER CONTAINING BENZOYL PEROXIDE
1.3. Details of the supplier of the safety data sheet
Company name: U-POL Limited
Tel: +44-(0)-1933 230300
Fax: +44-(0)-1933 425797
1.4. Emergency telephone number
Emergency tel: +44-(0)-1933 230310
Section 2: Hazards identification
2.1. Classification of the substance or mixture
Classification under CHIP: Xi: R36; Sens.: R43; -: R52/53; O: R7
Most important adverse effects: Irritating to eyes. May cause sensitisation by skin contact. Harmful to aquatic organisms,
may cause long-term adverse effects in the aquatic environment. May cause fire. Classification under CLP: This product has no classification under CLP.
2.2. Label elements
Label elements under CHIP:
Hazard symbols: Irritant.
Risk phrases: R36: Irritating to eyes.
SAFETY DATA SHEET
R43: May cause sensitisation by skin contact.
R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the Safety phrases: S24: Avoid contact with skin.
S3/7: Keep container tightly closed in a cool place.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek S36/37/39: Wear suitable protective clothing, gloves and eye / face protection.
2.3. Other hazards
PBT: This substance is not identified as a PBT substance.
Section 3: Composition/information on ingredients
3.2. Mixtures
Hazardous ingredients:
Section 4: First aid measures
4.1. Description of first aid measures
Skin contact: Wash immediately with plenty of soap and water. Remove all contaminated clothes and
footwear immediately unless stuck to skin. Eye contact: Bathe the eye with running water for 15 minutes. Transfer to hospital for specialist
Ingestion: Do not induce vomiting. Wash out mouth with water. Transfer to hospital as soon as
4.2. Most important symptoms and effects, both acute and delayed
Skin contact: There may be irritation and redness at the site of contact.
Eye contact: There may be irritation and pain.
Ingestion: There may be soreness and redness of the mouth and throat. Nausea and stomach
Inhalation: No symptoms.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.
SAFETY DATA SHEET
4.3. Indication of any immediate medical attention and special treatment needed
Immediate / special treatment: Eye bathing equipment should be available on the premises.
Section 5: Fire-fighting measures
5.1. Extinguishing media
Extinguishing media: Carbon dioxide. Dry chemical powder. Alcohol or polymer foam.
5.2. Special hazards arising from the substance or mixture
Exposure hazards: In combustion emits toxic fumes of carbon dioxide / carbon monoxide. Oxidising.
5.3. Advice for fire-fighters
Advice for fire-fighters: Wear self-contained breathing apparatus.
Section 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions: Refer to section 8 of SDS for personal protection details.
6.2. Environmental precautions
Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.
6.3. Methods and material for containment and cleaning up
Clean-up procedures: Absorb into dry earth or sand. Wash the spillage site with large amounts of water.
6.4. Reference to other sections
Reference to other sections: Refer to section 8 of SDS.
Section 7: Handling and storage
7.1. Precautions for safe handling
Handling requirements: Ensure there is sufficient ventilation of the area.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions: Store in cool, well ventilated area. Keep away from sources of ignition. Keep container
Suitable packaging: Must only be kept in original packaging.
7.3. Specific end use(s)
Specific end use(s): No data available.
Section 8: Exposure controls/personal protection
8.1. Control parameters
SAFETY DATA SHEET
Workplace exposure limits:
Respirable dust
Hazardous ingredients:
DIBENZOYL PEROXIDE
Workplace exposure limits:
Respirable dust
8.2. Exposure controls
Engineering measures: Ensure there is sufficient ventilation of the area.
Respiratory protection: Respiratory protection not required.
Hand protection: Nitrile gloves.
Eye protection: Safety goggles. Ensure eye bath is to hand.
Skin protection: Protective clothing. Rubber apron.
Section 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
State: Paste
Colour: Red
Odour: Barely perceptible odour
Evaporation rate: Negligible
Oxidising: Oxidising (by EC criteria)
Solubility in water: Insoluble
Viscosity: Viscous
Kinematic viscosity: 1000cps
Autoflammability°C: >380
Relative density: 1.2
VOC g/l: 274
9.2. Other information
Other information: Not applicable.
Section 10: Stability and reactivity
10.1. Reactivity
Reactivity: Stable under recommended transport or storage conditions.
10.2. Chemical stability
Chemical stability: Stable under normal conditions. SADT (Self-Accelerating Decomposition Temperature)
SAFETY DATA SHEET
10.3. Possibility of hazardous reactions
Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.
Decomposition may occur on exposure to conditions or materials listed below. 10.4. Conditions to avoid
Conditions to avoid: Direct sunlight. Heat. Hot surfaces. Sources of ignition.
10.5. Incompatible materials
Materials to avoid: Reducing agents. Acids. Bases. Metals.
10.6. Hazardous decomposition products
Haz. decomp. products: In combustion emits toxic fumes.
Section 11: Toxicological information
11.1. Information on toxicological effects
Relevant effects for mixture:
Symptoms / routes of exposure
Skin contact: There may be irritation and redness at the site of contact.
Eye contact: There may be irritation and pain.
Ingestion: There may be soreness and redness of the mouth and throat. Nausea and stomach
Inhalation: No symptoms.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.
Section 12: Ecological information
12.1. Toxicity
Ecotoxicity values: Not applicable.
12.2. Persistence and degradability
Persistence and degradability: Biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential: No data available.
12.4. Mobility in soil
Mobility: Insoluble in water.
SAFETY DATA SHEET
12.5. Results of PBT and vPvB assessment
PBT identification: This substance is not identified as a PBT substance.
12.6. Other adverse effects
Other adverse effects: Harmful to aquatic organisms.
Section 13: Disposal considerations
13.1. Waste treatment methods
Disposal operations: Incineration on land.
Disposal of packaging: Dispose of in a regulated landfill site or other method for hazardous or toxic wastes.
NB: The user's attention is drawn to the possible existence of regional or national
Section 14: Transport information
14.1. UN number
UN number: UN3108
14.2. UN proper shipping name
Shipping name: ORGANIC PEROXIDE, TYPE E, SOLID
14.3. Transport hazard class(es)
Transport class: 5.2
14.4. Packing group
14.5. Environmental hazards
Environmentally hazardous: No
Marine pollutant: No
14.6. Special precautions for user
Special precautions: No special precautions.
Tunnel code: D
Transport category: 2
Section 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.2. Chemical Safety Assessment
Chemical safety assessment: A chemical safety assessment has not been carried out for the substance or the mixture
Section 16: Other information
Other information
Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No
SAFETY DATA SHEET
FOR PROFESSIONAL USE ONLY. Read full instructions before use.
IMPORTANT: This product contains hazardous materials and therefore appropriate personal protective equipment should always be used.
Please refer to the label and consult the material safety data sheet for full handling instructions and personal protection information. These are available via your local stockist or via the U-POL website at .
U-POL disclaim any liability where the user does not wear the recommended personal Phrases used in s.2 and 3: H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
R3: Extreme risk of explosion by shock, friction, fire or other sources of ignition.
R43: May cause sensitisation by skin contact.
R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive
and shall be used only as a guide. Addition of reducers, hardeners and other additives over and above U-POL's recommendations for use, may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, this company shall not be held liable for any damage resulting from handling or from

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