Ictp.csic.es

Dr. Isabel Quijada Garrido Tenured Researcher Department of Physical Chemistry of Polymers Institute of Polymer Science and Technology C/Juan de la Cierva 3, Madrid 28006, Spain Tel.: +34-91-5622900 ext 254 Fax: +34-91-5644853 E-mail:[email protected] Isabel Quijada is currently Tenured Research (2007) at the Institute of Polymer Science and Technology (ICTP) at the Spanish National Research Council (CSIC) in Madrid. She received her Ph.D. (1996) at the Universidad Complutense of Madrid working at the ICTP on the diffusion of additives in polypropylene and nylon 12 and studding the behaviour of their blends. After her Ph D. degree, she made a post doc stay at the Max Planck Institute for Polymer Research in Mainz under the supervision of Prof. Hans W. Spiess and Manfred Wilhelm. She spent two years (1997-1999) at the Institute for Macromolecular Chemistry of Freiburg (Germany) in the group of Prof. Claudia Schmidt. During her post-doc in Freiburg she was involved on the study of the rheological behaviour of some thermotropic side-chain liquid crystal polymers and lyotropic surfactant solutions. Since 2007 she belongs to the staff of the CSIC as a Tenured Researcher. Her research group works on the development, characterization and applications of stimuli-sensitive polymers, and on the development of intelligent and biodegradable polymers. Exploiting advanced techniques, such as MRI (nuclear magnetic resonance imaging), they have investigated the swelling kinetics and diffusion of drugs as function of external stimuli. Biocompatible and biodegradable substrates based on polyhydroxyalkanoates (PHAs) have been modified for tissue engineering applications (bladder and bond regeneration). They are also working on methodologies for the surface modification of PHAs with thermo-sensitive polymers to control cell adhesion. Nowadays, they are developing methods to integrate stimuli-sensitive polymers with micro- and nano-structured materials. Publications:
García-Aparicio, C.; Quijada-Garrido, I.; Garrido, L. Diffusion of small molecules in a chitosan/water gel determined by proton localized NMR spectroscopy Mora-Barrantes, I.; López Valentin, J.; Rodriguez, A.; Quijada-Garrido, I.; Paris, R. Poly(styrene)/silica hybrid nanoparticles prepared via ATRP as high-quality fillers in elastomeric composites. García-García, J.; López, L. Paris, R., Surface modification of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) copolymer films for promoting interaction with bladder urothelial cells. • París, R.; Liras, M.; Quijada-Garrido, I. Thermo-Responsive behaviour of mixtures of epoxy functionalized oligo(ethylene glycol) methacrylate copolymers • Bernal MM, Liras M, Verdejo R, López-Manchado MA, Quijada-Garrido I, París R. 2011. Modification of carbon nanotubes with well-controlled fluorescent styrene-based polymers using the Diels-Alder reaction.52: 5739-5745. • García-García JM, Liras M, Quijada-Garrido I, Gallardo A, París R. Swelling control in thermo- responsive hydrogels based on 2-(2-methoxyethoxy)ethyl methacrylate by crosslinking and copolymerization with N-isopropylacrylamide2011, 43: 887-892. • París, R.; Quijada-Garrido, I.; García, O.; Liras, M., BODIPY-conjugated thermo-sensitive fluorescent polymers based on 2-(2-methoxyethoxy)ethyl methacrylate.2011, 44 (1), 80-86 • Liras M, García-García JM, Quijada-Garrido I, Gallardo A, París R. 2011. Thermo-responsive allyl-functionalized 2-(2-methoxyethoxy)ethyl methacrylate-based polymers as versatile precursors for smart polymer conjugates and conetworks44: 3739-3745. • Liras, M; García, O.; Quijada-Garrido; I; París R., Transformation of the bromine-end group into thiol in (meth)acrylic polymers synthesized by atom transfer radical polymerization. 2011, 44, 1335–1339. • París, R; Quijada, I.; Synthesis and aggregation properties in water solution of comblike methacrylic polymers with oligo(propylene glycol)-block-oligo(ethylene glycol)) as side chains. • De Ojeda, J. M. B.; Quijada-Garrido, I.; Barrales-Rienda, J. M., Synthesis, characterization and properties of N-maleimide side-chain liquid crystalline copolymers. 49 (2), 495-510 • Medel, S.; Manuel García, J.; Garrido, L.; Quijada-Garrido, I.; París, R., Thermo- and pH- responsive gradient and block copolymers based on 2-(2-methoxyethoxy)ethyl methacrylate synthesized via atom transfer radical polymerization and the formation of thermoresponsive surf2011, 49 (3), 690-700 • París, R.; García, J.; Quijada-Garrido, I., Thermo- and pH-sensitive hydrogels based on 2-(2- methoxyethoxy)ethyl methacrylate and methacrylic acid. 2011, 60 (2), 178-185; • Frutos, G.; Prior-Cabanillas, A.; París, R.; Quijada-Garrido, I., A novel controlled drug delivery system based on pH-responsive hydrogels included in soft gelatin capsules.2010, 6 (12), 4650-4656 • París, R.; García, J. M.; Quijada-Garrido, I., Synthesis and characterization of a new acrylic polymeric ibuprofen prodru 2010, 117 (6), 3271-3276 • París, R.; Quijada-Garrido, I., Temperature- and pH-responsive behaviour of poly(2-(2- methoxyethoxy)ethyl methacrylate-co-N,N-dimethylaminoethyl methacrylate) hydrogels.2010, 46 (11), 2156-2163; • París, R.; Barrales-Rienda, J. M.; Quijada-Garrido, I., Dynamic swelling of hydrogels based on random terpolymers of N-isopropylacrylamide, methacrylic acid and poly(ethylene glycol) macromonome2009, 50 (9), 2065-2074 • París, R.; Quijada-Garrido, I., Swelling behaviour of thermo-sensitive hydrogels based on oligo(ethylene glycol) methacrylates. 2009, 45 (12), 3418-3425 • París, R.; Quijada-Garrido, I., Swelling and hydrolytic degradation behaviour of pH-responsive hydrogels of poly[(N-isopropylacrylamide)-co-(methacrylicacid)] crosslinked by biodegradable polycaprolactone chains.2009, 58 (4), 362-367 • Quijada-Garrido, I.; Prior-Cabanillas, A.; Paris, R.; Frutos, G.; Barrales-Rienda, J. M., Water transport properties of pH-responsive hydrogels based on poly(methacrylic acid) with polyether side chains by magnetic resonance imaging.2009, 210 (7), 520-530 • Siebert, H.; Quijada-Garrido, I.; Vermant, J.; Noirez, L.; Burghardt, W. R.; Schmidt, C., Director Orientation of Nematic Side-Chain Liquid Crystalline Polymers Under Shear Flow: Comparison of a Flow-Aligning and a Non-Flow-Aligning Polysiloxane.2007, 208 (19-20), 2161-2172. • Prior-Cabanillas, A.; Barrales-Rienda, J. M.; Frutos, G.; Quijada-Garrido, I., Swelling behaviour of hydrogels from methacrylic acid and poly(ethylene glycol) side chains by magnetic resonance
imaging.2007, 56, (4), 506-511.
• Quijada-Garrido, I.; Iglesias-Gonzalez, V.; Mazon-Arechederra, J. M.; Barrales-Rienda, J. M., The role played by the interactions of small molecules with chitosan and their transition
temperatures. Glass-forming liquids: 1,2,3-propantriol (glycerol).2007,
68, (1), 173-186.
• Quijada-Garrido, I.; Laterza, B.; Mazon-Arechederra, J. M.; Barrales-Rienda, J. M., Characteristic features of chitosan/glycerol blends dynamics.2006, 207, (19), 1742-1751.
• Quijada-Garrido, I.; Prior-Cabanillas, A.; Garrido, L.; Barrales-Rienda, J. M., Swelling monitorization of poly [(N-isopropylacrylamide)-co-(methacrylic acid)] copolymers by magnetic
resonance imaging.2005, 38, (17), 7434-7442.
• Sousa, R. G.; Prior-Cabanillas, A.; Quijada-Garrido, I.; Barrales-Rienda, J. M., Dependence of copolymer composition, swelling history, and drug concentration on the loading of diltiazem hydrochloride (DIL.HCl) into poly [(N-isopropylacrylamide)-co-(methacrylic acid)] hydrogels and its release behaviour from hydrogel slabs.2005, 102, (3), 595-606. • Prior-Cabanillas, A.; Quijada-Garrido, I.; Frutos, G.; Barralas-Rienda, J. M., Influence of the swelling history on the swelling kinetics of stimuli-responsive poly [(N-isopropylacrylamide)-
co-(methacrylic acid)] hydrogels.2005, 46, (3), 685-693.
• Díez-Pena, E.; Frutos, P.; Frutos, G.; Quijada-Garrido, I.; Barrales-Rienda, J. M., The influence of the copolymer composition on the diltiazem hydrochloride release from a series of pH-sensitive poly[(N-isopropylacrylamide)-co-(methacrylic acid)] hydrogels.2004, 5, (2). • Díez-Peña, E.; Quijada-Garrido, I.; Barrales-Rienda, J. M.; Schnell, I.; Spiess, H. W., Advanced 1H solid-state NMR spectroscopy on hydrogels, 1 - The effect of hydrogen bonding in the collapse of poly(methacrylic acid) (PMAA) hydrogels.2004, 205, (4), 430-437. • Díez-Peña, E.; Quijada-Garrido, I.; Barrales-Rienda, J. M.; Schnell, I.; Spiess, H. W., Advanced 1H solid-state NMR spectroscopy on hydrogels, 2 - The formation of hydrogen bonds in hydrogels based on N-isopropylacrylamide (N-iPAAm) and methacrylic acid (MAA). 4, 205, (4), 438-447. • Díez-Peña, E.; Quijada-Garrido, I.; Frutos, P.; Barrales-Rienda, J. M., Analysis of the swelling dynamics of crosslinked P(N-iPAAm-co-MAA) copolymers, the corresponding homopolymers
and their interpenetrating networks. Kinetics of water penetration into the gel above the pKa of
MAA comonomeric units.2003, 52, (6), 956-965.
• Diez-Pena, E.; Quijada-Garrido, I.; Barrales-Rienda, J. M., Analysis of the swelling dynamics of cross-linked P(N-iPAAm-co-MAA) copolymers and their homopolymers under acidic medium. A kinetics interpretation of the overshooting effect.2003, 36, (7), 2475-2483. • Siebert, H.; Becker, P.; Quijada-Garrido, I.; Grabowski, D. A.; Schmidt, C., In situ deuteron NMR investigations of sheared liquid crystalline polymers. 2002, 22, (2-3), 311-326.
• Diez-Pena, E.; Quijada-Garrido, I.; Barrales-Rienda, J. M., Hydrogen-bonding effects on the dynamic swelling of P(N-iPAAm-co-MAA) copolymers. A case of autocatalytic swelling kinetics. 35, (23), 8882-8888. • Diez-Pena, E.; Quijada-Garrido, I.; Barrales-Rienda, J. M., On the water swelling behaviour of poly(N-isopropylacrylamide) [P(N-iPAAm)], poly(methacrylic acid) [P(MAA)], their random copolymers and sequential interpenetrating polymer networks (IPNs).2002, 43, (16), 4341-4348. • Diez-Pena, E.; Quijada-Garrido, I.; Barrales-Rienda, J. M., Hydrogels based on N- isopropylacrylamide and methacrylic acid: thermal stability and glass transition behaviour.
, 48, (1), 83-91.
• Diez-Pena, E.; Quijada-Garrido, I.; Frutos, P.; Barrales-Rienda, J. M., Thermal properties of cross-linked poly(N-isopropylacrylamide) [P(N-iPAAm)], poly(methacrylic acid) [P(MAA)],
their random copolymers [P(N-iPAAm-co-MAA)], and sequential interpenetrating polymer
networks (IPNs)., 35, (7), 2667-2675.
• Diez-Pena, E.; Quijada-Garrido, I.; Barrales-Rienda, J. M.; Wilhelm, M.; Spiess, H. W., NMR studies of the structure and dynamics of polymer gels based on N-isopropylacrylamide (N-iPAAm) and methacrylic acid (MAA).2002, 203, (3), 491-502. • Cramer, S. E.; Quijada-Garrido, I.; Ulrich, R.; Barrales-Rienda, J. M.; Spiess, H. W., Dynamic mechanical and dielectric properties of ORMOCER (R) incorporating functionalized poly(styrene) latexes.2001, 39, (8), 860-867. • Quijada-Garrido, I.; Siebert, H.; Friedrich, C.; Schmidt, C., Flow behavior of two side-chain liquid crystal polymers studied by transient rheology.2000, 33, (10), 3844-3854. • de Velasco-Ruiz, M. F.; Quijada-Garrido, I.; Benavente, R.; Barrales-Rienda, J. M., Miscibility studies of erucamide (13-cis-docosenamide)/poly(laurolactam) (nylon 12) (PA-12) blends. 2000, 41, (15), 5819-5828. • Quijada-Garrido, I.; de Velasco-Ruiz, M. F.; Barrales-Rienda, J. M., Fickian diffusion of erucamide (13-cis-docosenamide) in poly(laurolactam) (Nylon 12) (PA-12).2000, 201, (3), 375-381. • Quijada-Garrido, I.; Siebert, H.; Becker, P.; Friedrich, C.; Schmidt, C., Transient rheological behavior of tumbling side-chain liquid crystal polymers and determination of their lambda parameters.1999, 38, (6), 495-502. • Quijada-Garrido, I.; Wilhelm, M.; Spiess, H. W.; Barrales-Rienda, J. M., Solid-state NMR studies of structure and dynamics of erucamide isotactic poly(propylene) blends. 8, 199, (6), 985-995. • QuijadaGarrido, I.; BarralesRienda, J. M.; Perena, J. M.; Frutos, G., Solubility of erucamide (13- cis-docosenamide) in isotactic poly(propylene) and thermal behaviour of their blends.1997, 38, (20), 5125-5135.
• QuijadaGarrido, I.; BarralesRienda, J. M.; Perena, J. M.; Frutos, G., Dynamic mechanical and dielectric behavior of erucamide (13-cis-docosenamide), isotactic poly(propylene), and their
blends.1997, 35, (10), 1473-1482.
• QuijadaGarrido, I.; BarralesRienda, J. M.; Espinoza, L. A.; Fierro, J. L. G., Desorption of erucamide vapor in vacuum from erucamide/isotactic polypropylene films.1996, 29, (27), 8791-8797. • QuijadaGarrido, I.; BarralesRienda, J. M.; Frutos, G., Diffusion of erucamide (13-cis- docosenamide) in isotactic polypropylene.1996, 29, (22), 7164-7176. • Frutos, G.; Quijada, I.; Barrales, J. M., Use of the Latin Square Design to Study the Influence of the Experimental Parameters on Erucamide Differential Scanning Calorimetric Curves.1994, 119, (7), 1547

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